Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction

Leilei Wu; Volkan Degirmenci; Pieter C. M. M. Magusin; Bartlomiej M. Szyja; Emiel J. M. Hensen

doi:10.1039/c2cc33994c

Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction

Leilei Wu
, Volkan Degirmenci
, Pieter C. M. M. Magusin
, Bartlomiej M. Szyja
, Emiel J. M. Hensen

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

120 Citations (Scopus)

Abstract

The dual template synthesis of zeolite SSZ-13 by use of trimethyl-adamantanammonium hydroxide and a diquaternary-ammonium mesoporogen induces considerable mesoporosity without impeding zeolite microporosity. The strongly improved accessibility of Bronsted sites in mesoporous SSZ-13 increases its stability during application as an acid catalyst in the methanol-to-olefins reaction.

Original language	English
Pages (from-to)	9492-9494
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	76
DOIs	https://doi.org/10.1039/c2cc33994c
Publication status	Published - 04 Oct 2012

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
General Chemistry

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10.1039/c2cc33994c

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title = "Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction",

abstract = "The dual template synthesis of zeolite SSZ-13 by use of trimethyl-adamantanammonium hydroxide and a diquaternary-ammonium mesoporogen induces considerable mesoporosity without impeding zeolite microporosity. The strongly improved accessibility of Bronsted sites in mesoporous SSZ-13 increases its stability during application as an acid catalyst in the methanol-to-olefins reaction.",

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AU - Wu, Leilei

AU - Degirmenci, Volkan

AU - Magusin, Pieter C. M. M.

AU - Szyja, Bartlomiej M.

AU - Hensen, Emiel J. M.

PY - 2012/10/4

Y1 - 2012/10/4

N2 - The dual template synthesis of zeolite SSZ-13 by use of trimethyl-adamantanammonium hydroxide and a diquaternary-ammonium mesoporogen induces considerable mesoporosity without impeding zeolite microporosity. The strongly improved accessibility of Bronsted sites in mesoporous SSZ-13 increases its stability during application as an acid catalyst in the methanol-to-olefins reaction.

AB - The dual template synthesis of zeolite SSZ-13 by use of trimethyl-adamantanammonium hydroxide and a diquaternary-ammonium mesoporogen induces considerable mesoporosity without impeding zeolite microporosity. The strongly improved accessibility of Bronsted sites in mesoporous SSZ-13 increases its stability during application as an acid catalyst in the methanol-to-olefins reaction.

U2 - 10.1039/c2cc33994c

DO - 10.1039/c2cc33994c

M3 - Article

SN - 1359-7345

VL - 48

SP - 9492

EP - 9494

JO - Chemical Communications

JF - Chemical Communications

IS - 76

ER -

Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction

Abstract

ASJC Scopus subject areas

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