Effect of weak hydrogen bonding and included solvent on the crystal structure of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2

P. Suman; P.W. Dyer; P.J. Dyson; Stuart James; J.W. Steed

Effect of weak hydrogen bonding and included solvent on the crystal structure of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2

P. Suman
, P.W. Dyer
, P.J. Dyson
, Stuart James
, J.W. Steed

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Crystallisation of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2 from dichloromethane-diethyl ether (1:1) affords two different solvates; trans-Pt{PPh2(C16H15)}(2)Cl-2. CH2Cl2 1 and trans-Pt{PPh2(C16H15)}(2)Cl-2. Et2O 2; the CH2Cl2 forms H-bonding interactions with the complex whereas the Et2O participates only in weak van der Waals interactions; these differences arise from the different hydrogen-bonding characteristics of each solvent.

Original language	English
Pages (from-to)	1311-1313
Number of pages	3
Journal	New Journal of Chemistry
Volume	22
Publication status	Published - 1998

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title = "Effect of weak hydrogen bonding and included solvent on the crystal structure of the square-planar complex trans-Pt\{PPh2(C16H15)\}(2)Cl-2",

abstract = "Crystallisation of the square-planar complex trans-Pt\{PPh2(C16H15)\}(2)Cl-2 from dichloromethane-diethyl ether (1:1) affords two different solvates; trans-Pt\{PPh2(C16H15)\}(2)Cl-2. CH2Cl2 1 and trans-Pt\{PPh2(C16H15)\}(2)Cl-2. Et2O 2; the CH2Cl2 forms H-bonding interactions with the complex whereas the Et2O participates only in weak van der Waals interactions; these differences arise from the different hydrogen-bonding characteristics of each solvent.",

author = "P. Suman and P.W. Dyer and P.J. Dyson and Stuart James and J.W. Steed",

year = "1998",

language = "English",

volume = "22",

pages = "1311--1313",

journal = "New Journal of Chemistry",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Effect of weak hydrogen bonding and included solvent on the crystal structure of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2

AU - Suman, P.

AU - Dyer, P.W.

AU - Dyson, P.J.

AU - James, Stuart

AU - Steed, J.W.

PY - 1998

Y1 - 1998

N2 - Crystallisation of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2 from dichloromethane-diethyl ether (1:1) affords two different solvates; trans-Pt{PPh2(C16H15)}(2)Cl-2. CH2Cl2 1 and trans-Pt{PPh2(C16H15)}(2)Cl-2. Et2O 2; the CH2Cl2 forms H-bonding interactions with the complex whereas the Et2O participates only in weak van der Waals interactions; these differences arise from the different hydrogen-bonding characteristics of each solvent.

AB - Crystallisation of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2 from dichloromethane-diethyl ether (1:1) affords two different solvates; trans-Pt{PPh2(C16H15)}(2)Cl-2. CH2Cl2 1 and trans-Pt{PPh2(C16H15)}(2)Cl-2. Et2O 2; the CH2Cl2 forms H-bonding interactions with the complex whereas the Et2O participates only in weak van der Waals interactions; these differences arise from the different hydrogen-bonding characteristics of each solvent.

M3 - Article

VL - 22

SP - 1311

EP - 1313

JO - New Journal of Chemistry

JF - New Journal of Chemistry

ER -

Effect of weak hydrogen bonding and included solvent on the crystal structure of the square-planar complex trans-Pt{PPh2(C16H15)}(2)Cl-2

Abstract

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