Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]

E.I. Rogers; B. Sljukic; Christopher Hardacre; R.G. Compton

doi:10.1002/elan.200804393

Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]

E.I. Rogers
, B. Sljukic
, Christopher Hardacre
, R.G. Compton

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The solubility of manganese in mercury was determined electrochemically via amalgamation and stripping in the room temperature ionic liquid n-hexyltriethylammonium bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]. A hemispherical mercury electrode was made by electrodepositing mercury onto a planar platinum microelectrode. Cyclic voltammetry of Mn2+ in [N-6,N-2,N-2,N-2][NTf2] at the mercury microhemisphere electrode was investigated at temperatures of 298, 303 and 313 K. The solubility of Mn in Hg was determined on the basis of the charge under the reduction peak (Mn2+ --> Mn-0) and the corresponding reoxidation.

Original language	English
Pages (from-to)	2603-2607
Number of pages	5
Journal	Electroanalysis
Volume	20
Issue number	24
DOIs	https://doi.org/10.1002/elan.200804393
Publication status	Published - Dec 2008

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

Access to Document

10.1002/elan.200804393

Fingerprint

Dive into the research topics of 'Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]'. Together they form a unique fingerprint.

Cite this

@article{05e29fd74e1441889c96b16945c4addf,

title = "Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]",

abstract = "The solubility of manganese in mercury was determined electrochemically via amalgamation and stripping in the room temperature ionic liquid n-hexyltriethylammonium bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]. A hemispherical mercury electrode was made by electrodepositing mercury onto a planar platinum microelectrode. Cyclic voltammetry of Mn2+ in [N-6,N-2,N-2,N-2][NTf2] at the mercury microhemisphere electrode was investigated at temperatures of 298, 303 and 313 K. The solubility of Mn in Hg was determined on the basis of the charge under the reduction peak (Mn2+ --> Mn-0) and the corresponding reoxidation.",

author = "E.I. Rogers and B. Sljukic and Christopher Hardacre and R.G. Compton",

year = "2008",

month = dec,

doi = "10.1002/elan.200804393",

language = "English",

volume = "20",

pages = "2603--2607",

journal = "Electroanalysis",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

number = "24",

}

Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]. / Rogers, E.I.; Sljukic, B.; Hardacre, Christopher et al.
In: Electroanalysis, Vol. 20, No. 24, 12.2008, p. 2603-2607.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]

AU - Rogers, E.I.

AU - Sljukic, B.

AU - Hardacre, Christopher

AU - Compton, R.G.

PY - 2008/12

Y1 - 2008/12

N2 - The solubility of manganese in mercury was determined electrochemically via amalgamation and stripping in the room temperature ionic liquid n-hexyltriethylammonium bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]. A hemispherical mercury electrode was made by electrodepositing mercury onto a planar platinum microelectrode. Cyclic voltammetry of Mn2+ in [N-6,N-2,N-2,N-2][NTf2] at the mercury microhemisphere electrode was investigated at temperatures of 298, 303 and 313 K. The solubility of Mn in Hg was determined on the basis of the charge under the reduction peak (Mn2+ --> Mn-0) and the corresponding reoxidation.

AB - The solubility of manganese in mercury was determined electrochemically via amalgamation and stripping in the room temperature ionic liquid n-hexyltriethylammonium bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]. A hemispherical mercury electrode was made by electrodepositing mercury onto a planar platinum microelectrode. Cyclic voltammetry of Mn2+ in [N-6,N-2,N-2,N-2][NTf2] at the mercury microhemisphere electrode was investigated at temperatures of 298, 303 and 313 K. The solubility of Mn in Hg was determined on the basis of the charge under the reduction peak (Mn2+ --> Mn-0) and the corresponding reoxidation.

UR - https://www.scopus.com/pages/publications/57849086907

U2 - 10.1002/elan.200804393

DO - 10.1002/elan.200804393

M3 - Article

SN - 1040-0397

VL - 20

SP - 2603

EP - 2607

JO - Electroanalysis

JF - Electroanalysis

IS - 24

ER -

Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this