Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs

E.I. Rogers; D.S. Silvester; S.E.W. Jones; Leigh Aldous; Christopher Hardacre; A.J. Russell; S.G. Davies; R.G. Compton

doi:10.1021/jp0737754

Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs

E.I. Rogers, D.S. Silvester, S.E.W. Jones, Leigh Aldous, Christopher Hardacre, A.J. Russell, S.G. Davies, R.G. Compton

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

The voltammetry and kinetics of the Ag vertical bar Ag+ system (commonly used as a reference electrode material in both protic/aprotic and RTIL solvents) was studied in the room-temperature ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C(4)mpyrr][NTf2] on a 10 mu m diameter Pt electrode. For the three silver salts investigated (AgOTf, AgNTf2, and AgNO3, where OTf- = trifluoromethanesulfonate, NTf2- = bis(trifluoromethylsulfonyl)imide, and NO3- = nitrate), the voltammetry gave rise to a redox couple characteristic of a

Original language	English
Pages (from-to)	13957-13966
Number of pages	10
Journal	Journal of Physical Chemistry C
Volume	111 (37)
Issue number	37
DOIs	https://doi.org/10.1021/jp0737754
Publication status	Published - 20 Aug 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
General Energy
Electronic, Optical and Magnetic Materials
Surfaces, Coatings and Films

Access to Document

10.1021/jp0737754

Fingerprint

Dive into the research topics of 'Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs'. Together they form a unique fingerprint.

Cite this

Rogers, E. I., Silvester, D. S., Jones, S. E. W., Aldous, L., Hardacre, C., Russell, A. J., Davies, S. G., & Compton, R. G. (2007). Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs. Journal of Physical Chemistry C, 111 (37)(37), 13957-13966. https://doi.org/10.1021/jp0737754

@article{775d139bf4e34aada3030ab325456921,

title = "Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs",

abstract = "The voltammetry and kinetics of the Ag vertical bar Ag+ system (commonly used as a reference electrode material in both protic/aprotic and RTIL solvents) was studied in the room-temperature ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C(4)mpyrr][NTf2] on a 10 mu m diameter Pt electrode. For the three silver salts investigated (AgOTf, AgNTf2, and AgNO3, where OTf- = trifluoromethanesulfonate, NTf2- = bis(trifluoromethylsulfonyl)imide, and NO3- = nitrate), the voltammetry gave rise to a redox couple characteristic of a",

author = "E.I. Rogers and D.S. Silvester and S.E.W. Jones and Leigh Aldous and Christopher Hardacre and A.J. Russell and S.G. Davies and R.G. Compton",

year = "2007",

month = aug,

day = "20",

doi = "10.1021/jp0737754",

language = "English",

volume = "111 (37)",

pages = "13957--13966",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

publisher = "American Chemical Society",

number = "37",

}

Rogers, EI, Silvester, DS, Jones, SEW, Aldous, L, Hardacre, C, Russell, AJ, Davies, SG & Compton, RG 2007, 'Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs', Journal of Physical Chemistry C, vol. 111 (37), no. 37, pp. 13957-13966. https://doi.org/10.1021/jp0737754

Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs. / Rogers, E.I.; Silvester, D.S.; Jones, S.E.W. et al.
In: Journal of Physical Chemistry C, Vol. 111 (37), No. 37, 20.08.2007, p. 13957-13966.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs

AU - Rogers, E.I.

AU - Silvester, D.S.

AU - Jones, S.E.W.

AU - Aldous, Leigh

AU - Hardacre, Christopher

AU - Russell, A.J.

AU - Davies, S.G.

AU - Compton, R.G.

PY - 2007/8/20

Y1 - 2007/8/20

N2 - The voltammetry and kinetics of the Ag vertical bar Ag+ system (commonly used as a reference electrode material in both protic/aprotic and RTIL solvents) was studied in the room-temperature ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C(4)mpyrr][NTf2] on a 10 mu m diameter Pt electrode. For the three silver salts investigated (AgOTf, AgNTf2, and AgNO3, where OTf- = trifluoromethanesulfonate, NTf2- = bis(trifluoromethylsulfonyl)imide, and NO3- = nitrate), the voltammetry gave rise to a redox couple characteristic of a

AB - The voltammetry and kinetics of the Ag vertical bar Ag+ system (commonly used as a reference electrode material in both protic/aprotic and RTIL solvents) was studied in the room-temperature ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C(4)mpyrr][NTf2] on a 10 mu m diameter Pt electrode. For the three silver salts investigated (AgOTf, AgNTf2, and AgNO3, where OTf- = trifluoromethanesulfonate, NTf2- = bis(trifluoromethylsulfonyl)imide, and NO3- = nitrate), the voltammetry gave rise to a redox couple characteristic of a

UR - http://www.scopus.com/inward/record.url?scp=34948815658&partnerID=8YFLogxK

U2 - 10.1021/jp0737754

DO - 10.1021/jp0737754

M3 - Article

SN - 1932-7447

VL - 111 (37)

SP - 13957

EP - 13966

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 37

ER -

Rogers EI, Silvester DS, Jones SEW, Aldous L, Hardacre C, Russell AJ et al. Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs. Journal of Physical Chemistry C. 2007 Aug 20;111 (37)(37):13957-13966. doi: 10.1021/jp0737754

Electrochemical kinetics of Ag vertical bar Ag+ and TMPD vertical bar TMPD+center dot in the room-temperature ionic liquid [C(4)mpyrr][NTf2]; toward optimizing reference electrodes for voltammetry in RTILs

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this