Electrochemical synthesis and characterization of conducting polymers using room temperature melt as an electrolyte

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7 Citations (Scopus)

Abstract

Aromatic monomers can be polymerised using the chloroaluminate room temperature melt obtained by mixing 1:2 ratio of cetyl pyridinium chloride and anhydrous aluminium chloride miscible in all proportions with organic solvents as an electrolyte. The chloroaluminate (AlCl4-) anion generated in this melt having a tetrahedral symmetry with equal bond lengths and bond angles is the dopant to stabilize macrocation generated near the vicinity of anode to yield better conducting and better ordered electronically conducting free standing polymer film. In this communication, we discuss the polymers derived from benzene and pyrrole and their characterization by various techniques.
Original languageEnglish
Pages (from-to)306-310
Number of pages5
JournalSynthetic Metals
Volume155 (2)
Issue number2
DOIs
Publication statusPublished - 15 Nov 2005

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

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