The cathodic and anodic: potential limit of eleven different ionic liquids were determined at a mercury hemisphere electrode. Ionic liquids containing the phosphonium cation (tri(n-hexyl)tetradecylphosphonium, [P-14.6,P-6.6](+)) give the largest potential window, especially When Coupled to a trifluorotris(pentafluoroethyl)- [FAP](-). or bis(trifluoromethanesulfonyl)imide, [NTf2](-), anion.
ASJC Scopus subject areas
- Chemical Engineering(all)
Rogers, E. I., Sljukic, B., Hardacre, C., & Compton, R. G. (2009). Electrochemistry in Room-Temperature Ionic Liquids: Potential Windows at Mercury Electrodes. Journal of Chemical and Engineering Data, 54(7), 2049-2053. https://doi.org/10.1021/je800898z