Electrochemistry in Room-Temperature Ionic Liquids: Potential Windows at Mercury Electrodes

E.I. Rogers; B. Sljukic; Christopher Hardacre; R.G. Compton

doi:10.1021/je800898z

Electrochemistry in Room-Temperature Ionic Liquids: Potential Windows at Mercury Electrodes

E.I. Rogers, B. Sljukic, Christopher Hardacre, R.G. Compton

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

90 Citations (Scopus)

Abstract

The cathodic and anodic: potential limit of eleven different ionic liquids were determined at a mercury hemisphere electrode. Ionic liquids containing the phosphonium cation (tri(n-hexyl)tetradecylphosphonium, [P-14.6,P-6.6](+)) give the largest potential window, especially When Coupled to a trifluorotris(pentafluoroethyl)- [FAP](-). or bis(trifluoromethanesulfonyl)imide, [NTf2](-), anion.

Original language	English
Pages (from-to)	2049-2053
Number of pages	5
Journal	Journal of Chemical and Engineering Data
Volume	54
Issue number	7
DOIs	https://doi.org/10.1021/je800898z
Publication status	Published - 09 Jul 2009

ASJC Scopus subject areas

General Chemical Engineering
General Chemistry

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abstract = "The cathodic and anodic: potential limit of eleven different ionic liquids were determined at a mercury hemisphere electrode. Ionic liquids containing the phosphonium cation (tri(n-hexyl)tetradecylphosphonium, [P-14.6,P-6.6](+)) give the largest potential window, especially When Coupled to a trifluorotris(pentafluoroethyl)- [FAP](-). or bis(trifluoromethanesulfonyl)imide, [NTf2](-), anion.",

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AB - The cathodic and anodic: potential limit of eleven different ionic liquids were determined at a mercury hemisphere electrode. Ionic liquids containing the phosphonium cation (tri(n-hexyl)tetradecylphosphonium, [P-14.6,P-6.6](+)) give the largest potential window, especially When Coupled to a trifluorotris(pentafluoroethyl)- [FAP](-). or bis(trifluoromethanesulfonyl)imide, [NTf2](-), anion.

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Electrochemistry in Room-Temperature Ionic Liquids: Potential Windows at Mercury Electrodes

Abstract

ASJC Scopus subject areas

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