Enantiomeric programming in tripodal transition metal scaffolds

Nicholas Fletcher; C. Martin; H.J. Abraham

doi:10.1039/b703761a

Enantiomeric programming in tripodal transition metal scaffolds

Nicholas Fletcher, C. Martin, H.J. Abraham

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A new route to the isolation of the enantiopure tris- chelate complex (Delta/Lambda)- fac-[Ru( L-1)(3)] 21 (where L-1 is 2,2'-bipyridine-5-carboxylic acid) is demonstrated, where the transition metal centre retains the memory of the chirality present in a simple tripodal tether used to control the metal centred geometry.

Original language	English
Pages (from-to)	1407-1411
Number of pages	5
Journal	New Journal of Chemistry
Volume	31
Issue number	8
DOIs	https://doi.org/10.1039/b703761a
Publication status	Published - May 2007

ASJC Scopus subject areas

General Chemistry

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10.1039/b703761a

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title = "Enantiomeric programming in tripodal transition metal scaffolds",

abstract = "A new route to the isolation of the enantiopure tris- chelate complex (Delta/Lambda)- fac-[Ru( L-1)(3)] 21 (where L-1 is 2,2'-bipyridine-5-carboxylic acid) is demonstrated, where the transition metal centre retains the memory of the chirality present in a simple tripodal tether used to control the metal centred geometry.",

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AB - A new route to the isolation of the enantiopure tris- chelate complex (Delta/Lambda)- fac-[Ru( L-1)(3)] 21 (where L-1 is 2,2'-bipyridine-5-carboxylic acid) is demonstrated, where the transition metal centre retains the memory of the chirality present in a simple tripodal tether used to control the metal centred geometry.

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Enantiomeric programming in tripodal transition metal scaffolds

Abstract

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