Enhanced photocatalytic degradation of 2-methyl-4-chlorophenoxyacetic acid (MCPA) by the addition of H2O2

Jamie Kelly, Ciara McDonnell, Nathan Skillen, Panagiotis Manesiotis, Peter Robertson

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)
34 Downloads (Pure)


Photocatalytic remediation technology has been shown to be a favorable approach for the removal of a range of environmental pollutants in water treatment. While this approach can often achieve complete degradation, often overlooked are reaction intermediates that are potentially as harmful as the original parent compound. In the case of photocatalytic oxidation of the herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA), we have recently shown that 4-chloro-2-methylphenol (CMP) is formed as the primary intermediate. To ensure the continued development of the technology, it is crucial to ensure the removal of both MCPA and CMP can be achieved by photocatalysis. Reported here is the enhanced photocatalytic removal and subsequent suppression of MCPA and CMP respectively, by the addition of small quantities of H2O2. While the addition of H2O2 often accelerates degradation rates (via increased OH radical production), it was found to restrict the formation of CMP in this study through competitive adsorption at the surface of TiO2. Based on the combination of MCPA removal coupled with supressed CMP formation, 0.5% H2O2 was determined to be an optimal loading for the process. Under these conditions 100% MCPA removal was achieved (to the limit of HPLC detection) after 45 min irradiation at a degradation rate of ∼1 mg L−1 min−1 (ƞphoton = 4.4), which also resulted in a ∼83% reduction in CMP formation when compared to a system with no H2O2 present.
Original languageEnglish
Article number130082
Early online date23 Feb 2021
Publication statusPublished - Jul 2021


  • Photocatalytic remediation
  • 2-Methyl-4-chlorophenoxyacetic acid, Hydrogen peroxide, Low power irradiation, Photoreactor technology
  • Hydrogen peroxide
  • Low power irradiation
  • Photoreactor technology


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