Here we provide definitive EPR evidence for the existence of α-triphenylstannylvinyl radicals such as (Z)-2 in the low temperature O-directed free radical hydrostannation of dialkyl propargylic alcohols with Ph3SnH/cat. Et3B and O2 in PhMe.
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Further investigations into the mechanism of the o-directed free radical hydrostannation of alkyl and aryl acetylenesAuthor: Watson, H., Jul 2022
Supervisor: Stevenson, P. (Supervisor) & Hale, K. (Supervisor)
Student thesis: Doctoral Thesis › Doctor of Philosophy