Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators

Pengfei Zhao, Navneet Soin, Amit Kumar, Lin Shi, Shaoliang Guan, Christos Tsonos, Zidong Yu, Sekhar Chandra Ray, James McLaughlin, Zhigang Zhu, Erping Zhou, Junfeng Geng, Chan H. See, Jikui Luo

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Abstract

The rapid uptake of energy harvesting triboelectric nanogenerators (TENGs) for self-powered electronics requires the development of high-performance tribo-materials capable of providing large power outputs. This work reports on the synthesis and use of aniline formaldehyde resin (AFR) for energy-harvesting applications. The facile, acidic-medium reaction between aniline and formaldehyde produces the aniline-formaldehyde condensate, which upon an in-vacuo high temperature curing step provides smooth AFR films with
abundant positively-charged nitrogen and oxygen surface functional groups, endowing AFR with a significantly higher positive tribo-polarity than the existing state-of-art polyamide-6 (PA6). A TENG comprising of optimized thin-layered AFR against a polytetrafluoroethylene (PTFE) film produced a peak-to-peak voltage of up to ~1,000 V, a current density of ~65 mA m-2, a transferred charge density of ~200 μC m-2 and an instantaneous power output (energy
pulse) of ~11 W m-2 (28.1 μJ cycle-1), respectively. The suitability of AFR was further supported through the scanning Kelvin probe force microscopy (SKPFM) measurements, which reveal a significantly higher surface potential value of 1.147 V for AFR as compared to 0.87 V for PA6 and a step-by-step increase of the surface potential with the increase of energy generation cycles. The work not only proposes a novel mouldable AFR synthesis process but also expands with excellent prospects, the current portfolio of tribo-positive materials for triboelectric energy harvesting applications.
Original languageEnglish
Article number104291
Number of pages13
JournalNano Energy
Volume67
Issue number104291
Early online date14 Nov 2019
DOIs
Publication statusPublished - Jan 2020

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    Zhao, P., Soin, N., Kumar, A., Shi, L., Guan, S., Tsonos, C., Yu, Z., Ray, S. C., McLaughlin, J., Zhu, Z., Zhou, E., Geng, J., See, C. H., & Luo, J. (2020). Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators. Nano Energy, 67(104291), [104291]. https://doi.org/10.1016/j.nanoen.2019.104291