TY - JOUR
T1 - Factors affecting luminescence and aurophilicity on digold(l) complexes and their potential as cation probes
AU - Lagunas, M. Cristina
AU - Mendicute Fierro, Claudio
AU - Pintado-Alba, Aranzazu
AU - de la Riva, Héctor
AU - Betanzos-Lara, Soledad
PY - 2007/7/4
Y1 - 2007/7/4
N2 - In the last few years we have analysed the factors that affect the structures and luminescence properties of Au(I) compounds, specifically in relation with the presence of aurophilic contacts and their application as cation probes. EXAFS studies have allowed us to obtain for the first time direct structural data of dissolved Au(I) compounds. An overview of the work reported to date is presented here. The optical properties of complex [Au2Cl2(μ-dpephos)] (dpephos = bis(2-diphenylphosphino) phenylether, 1) have been revisited and new results are now included. New aspects on the use of the complexes as Ag(I) probes are also discussed.
AB - In the last few years we have analysed the factors that affect the structures and luminescence properties of Au(I) compounds, specifically in relation with the presence of aurophilic contacts and their application as cation probes. EXAFS studies have allowed us to obtain for the first time direct structural data of dissolved Au(I) compounds. An overview of the work reported to date is presented here. The optical properties of complex [Au2Cl2(μ-dpephos)] (dpephos = bis(2-diphenylphosphino) phenylether, 1) have been revisited and new results are now included. New aspects on the use of the complexes as Ag(I) probes are also discussed.
UR - http://www.scopus.com/inward/record.url?scp=34948911488&partnerID=8YFLogxK
U2 - 10.1007/BF03215570
DO - 10.1007/BF03215570
M3 - Review article
AN - SCOPUS:34948911488
VL - 40
SP - 135
EP - 141
JO - GOLD BULLETIN
JF - GOLD BULLETIN
SN - 0017-1557
IS - 2
ER -