Ferrocenyl derivatives with Mo(TpAn) units for second- and third-order nonlinear optical applications

G. Rojo; F. Agulló-López; J. A. Campo; M. Cano; M. C. Lagunas; J. V. Heras

doi:10.1016/S0379-6779(01)00446-5

Ferrocenyl derivatives with Mo(Tp^An) units for second- and third-order nonlinear optical applications

G. Rojo, F. Agulló-López, J. A. Campo, M. Cano^*, M. C. Lagunas, J. V. Heras

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

New molecular systems based on donor/acceptor organometallic groups connected by π-conjugated bridges have been designed and their nonlinear optical (NLO) properties investigated. At macroscopic level SHG and THG responses were measured on corona-poled spin-coated films and at molecular level cubic hyperpolarizability data were obtained from solution. For comparison related compounds having NO₂ as acceptor group were also analyzed. New trends have been derived from the analysis of the molecular characteristics: nature of the acceptor and structural variations on the bridge.

Original language	English
Pages (from-to)	201-203
Number of pages	3
Journal	Synthetic Metals
Volume	124
Issue number	1
DOIs	https://doi.org/10.1016/S0379-6779(01)00446-5
Publication status	Published - 22 Oct 2001
Externally published	Yes
Event	Molecular Photonics: from Macroscopic to Nanoscopic Applications (EMRS Proceedings Symposium H) - Strasbourg, France Duration: 30 May 2000 → 02 Jun 2000

Keywords

Guest-host films
Organometallics for NLO
Second- and third-harmonic generation

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/S0379-6779(01)00446-5

Cite this

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title = "Ferrocenyl derivatives with Mo(TpAn) units for second- and third-order nonlinear optical applications",

abstract = "New molecular systems based on donor/acceptor organometallic groups connected by π-conjugated bridges have been designed and their nonlinear optical (NLO) properties investigated. At macroscopic level SHG and THG responses were measured on corona-poled spin-coated films and at molecular level cubic hyperpolarizability data were obtained from solution. For comparison related compounds having NO2 as acceptor group were also analyzed. New trends have been derived from the analysis of the molecular characteristics: nature of the acceptor and structural variations on the bridge.",

keywords = "Guest-host films, Organometallics for NLO, Second- and third-harmonic generation",

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AU - Rojo, G.

AU - Agulló-López, F.

AU - Campo, J. A.

AU - Cano, M.

AU - Lagunas, M. C.

AU - Heras, J. V.

PY - 2001/10/22

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AB - New molecular systems based on donor/acceptor organometallic groups connected by π-conjugated bridges have been designed and their nonlinear optical (NLO) properties investigated. At macroscopic level SHG and THG responses were measured on corona-poled spin-coated films and at molecular level cubic hyperpolarizability data were obtained from solution. For comparison related compounds having NO2 as acceptor group were also analyzed. New trends have been derived from the analysis of the molecular characteristics: nature of the acceptor and structural variations on the bridge.

KW - Guest-host films

KW - Organometallics for NLO

KW - Second- and third-harmonic generation

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