Formation of nickel-thiolate aggregates via reaction with CH2Cl2

Q. Wang, Andrew Marr, A.J. Blake, C. Wilson, M. Schroder

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

Reaction of the mononuclear nickel-thiolate complex [Ni(L-1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex Ni5Cl2(L-1)(4)(dppe)(2)], while [Ni(L-1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L-2)(dcpe)(2)] in which two L-1 units are linked by a methylene group derived from CH2Cl2.
Original languageEnglish
Pages (from-to)2776-2777
Number of pages2
JournalChemical Communications
Volume2003
DOIs
Publication statusPublished - 2003

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