Formation of nickel-thiolate aggregates via reaction with CH2Cl2

Q. Wang; Andrew Marr; A.J. Blake; C. Wilson; M. Schroder

doi:10.1039/b309523a

Formation of nickel-thiolate aggregates via reaction with CH2Cl2

Q. Wang, Andrew Marr, A.J. Blake, C. Wilson, M. Schroder

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Reaction of the mononuclear nickel-thiolate complex [Ni(L-1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex Ni5Cl2(L-1)(4)(dppe)(2)], while [Ni(L-1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L-2)(dcpe)(2)] in which two L-1 units are linked by a methylene group derived from CH2Cl2.

Original language	English
Pages (from-to)	2776-2777
Number of pages	2
Journal	Chemical Communications
Volume	2003
DOIs	https://doi.org/10.1039/b309523a
Publication status	Published - 2003

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10.1039/b309523a

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title = "Formation of nickel-thiolate aggregates via reaction with CH2Cl2",

abstract = "Reaction of the mononuclear nickel-thiolate complex [Ni(L-1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex Ni5Cl2(L-1)(4)(dppe)(2)], while [Ni(L-1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L-2)(dcpe)(2)] in which two L-1 units are linked by a methylene group derived from CH2Cl2.",

author = "Q. Wang and Andrew Marr and A.J. Blake and C. Wilson and M. Schroder",

year = "2003",

doi = "10.1039/b309523a",

language = "English",

volume = "2003",

pages = "2776--2777",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Formation of nickel-thiolate aggregates via reaction with CH2Cl2

AU - Wang, Q.

AU - Marr, Andrew

AU - Blake, A.J.

AU - Wilson, C.

AU - Schroder, M.

PY - 2003

Y1 - 2003

N2 - Reaction of the mononuclear nickel-thiolate complex [Ni(L-1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex Ni5Cl2(L-1)(4)(dppe)(2)], while [Ni(L-1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L-2)(dcpe)(2)] in which two L-1 units are linked by a methylene group derived from CH2Cl2.

AB - Reaction of the mononuclear nickel-thiolate complex [Ni(L-1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex Ni5Cl2(L-1)(4)(dppe)(2)], while [Ni(L-1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L-2)(dcpe)(2)] in which two L-1 units are linked by a methylene group derived from CH2Cl2.

U2 - 10.1039/b309523a

DO - 10.1039/b309523a

M3 - Article

SN - 1359-7345

VL - 2003

SP - 2776

EP - 2777

JO - Chemical Communications

JF - Chemical Communications

ER -

Formation of nickel-thiolate aggregates via reaction with CH2Cl2

Abstract

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