Halogen-bond mediated efficient storage of extremely volatile perfluoroiodides in ionic liquids

Delphine Gaspard, Kenneth R. Seddon, Peter K. J. Robertson, H. Q. Nimal Gunaratne

Research output: Contribution to journalArticle

3 Citations (Scopus)
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Abstract

Highly volatile and valuable reagents, perfluoroiodides were shown to complex with ionic liquids with aid of a halogen-bond between a diverse set of anions and electrophilic iodine atom in perfluorinated iodides. The affinity of anions in various ionic liquids towards perfluoroiodides was examined by 19F NMR. Making use of the non-volatility of ionic liquids, we demonstrate here, perfluoroiodides can be stored and released controllably, on demand, from an ionic liquid matrix.
Original languageEnglish
JournalChemical Communications
Early online date12 Jul 2019
DOIs
Publication statusEarly online date - 12 Jul 2019

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