Abstract
| Original language | English |
|---|---|
| Journal | Chemical Communications |
| Early online date | 12 Jul 2019 |
| DOIs | |
| Publication status | Early online date - 12 Jul 2019 |
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Halogen-bond mediated efficient storage of extremely volatile perfluoroiodides in ionic liquids. / Gaspard, Delphine ; Seddon, Kenneth R.; Robertson, Peter K. J.; Gunaratne, H. Q. Nimal.
In: Chemical Communications, 12.07.2019.Research output: Contribution to journal › Article
TY - JOUR
T1 - Halogen-bond mediated efficient storage of extremely volatile perfluoroiodides in ionic liquids
AU - Gaspard, Delphine
AU - Seddon, Kenneth R.
AU - Robertson, Peter K. J.
AU - Gunaratne, H. Q. Nimal
PY - 2019/7/12
Y1 - 2019/7/12
N2 - Highly volatile and valuable reagents, perfluoroiodides were shown to complex with ionic liquids with aid of a halogen-bond between a diverse set of anions and electrophilic iodine atom in perfluorinated iodides. The affinity of anions in various ionic liquids towards perfluoroiodides was examined by 19F NMR. Making use of the non-volatility of ionic liquids, we demonstrate here, perfluoroiodides can be stored and released controllably, on demand, from an ionic liquid matrix.
AB - Highly volatile and valuable reagents, perfluoroiodides were shown to complex with ionic liquids with aid of a halogen-bond between a diverse set of anions and electrophilic iodine atom in perfluorinated iodides. The affinity of anions in various ionic liquids towards perfluoroiodides was examined by 19F NMR. Making use of the non-volatility of ionic liquids, we demonstrate here, perfluoroiodides can be stored and released controllably, on demand, from an ionic liquid matrix.
U2 - 10.1039/C9CC04198B
DO - 10.1039/C9CC04198B
M3 - Article
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
ER -