Abstract
Highly volatile and valuable reagents, perfluoroiodides were shown to complex with ionic liquids with aid of a halogen-bond between a diverse set of anions and electrophilic iodine atom in perfluorinated iodides. The affinity of anions in various ionic liquids towards perfluoroiodides was examined by 19F NMR. Making use of the non-volatility of ionic liquids, we demonstrate here, perfluoroiodides can be stored and released controllably, on demand, from an ionic liquid matrix.
Original language | English |
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Journal | Chemical Communications |
Early online date | 12 Jul 2019 |
DOIs | |
Publication status | Early online date - 12 Jul 2019 |