Abstract
We report the design of stable, ionic liquid-hybrids, covalently-anchored to the framework architectures of microporous and hierarchical solid supports. The ionic liquid moieties that are anchored to the framework facilitate enhanced mass-transport, and afford superior catalytic performance in the Beckmann rearrangement of cyclic oximes at low-temperatures. The ionic liquid-metal oxide (IL-MO) hybrids also play an important role in modifying the reaction pathway and synergistic enhancements in catalytic properties are attributed to the increased hydrophobicity of the anchored, imidazolium-based ionic liquid.
Original language | English |
---|---|
Pages (from-to) | 1-36 |
Journal | ACS Sustainable Chemistry & Engineering |
Early online date | 29 Oct 2018 |
DOIs | |
Publication status | Early online date - 29 Oct 2018 |
Fingerprint Dive into the research topics of 'Heterogenized ionic liquid-metal oxide hybrids: enhanced catalytic activity in the liquid-phase Beckmann rearrangement'. Together they form a unique fingerprint.
Profiles
-
Andrew Marr
- School of Chemistry and Chemical Engineering - Senior Lecturer
- Organic Synthesis and Chemical Biology
Person: Academic