High energy resolution fluorescence detection XANES - an in situ method to study the interaction of adsorbed molecules with metal catalysts in the liquid phase

Haresh G. Manyar*, Richard Morgan, Kevin Morgan, Bo Yang, P. Hu, Jakub Szlachetko, Jacinto Sa, Christopher Hardacre

*Corresponding author for this work

Research output: Contribution to journalArticle

21 Citations (Scopus)
234 Downloads (Pure)

Abstract

The change in the Pt electronic structure following the adsorption of an a,ß-unsaturated aldehyde and ketone was followed by in situ HERFD-XANES in the liquid phase. The resulting shift in the Pt Fermi energy is in good agreement with the molecule adsorption energy trends calculated by DFT and provides insight into the reaction selectivity.
Original languageEnglish
Pages (from-to)1497-1500
Number of pages4
JournalCatalysis, Science & technology
Volume3
Issue number6
Early online date09 Apr 2013
DOIs
Publication statusPublished - 2013

Keywords

  • X-RAY SPECTROSCOPY
  • ALPHA,BETA-UNSATURATED ALDEHYDES
  • SELECTIVE HYDROGENATION

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