Abstract
The highly syn-selective hydrosilylation of allylic alcohols was developed which, following oxidation, provided 1,3 alcohols containing two contiguous stereocentres. Through judicious choice of silane the complementary anti-selective hydrosilylation was also developed. This protocol was applied to the synthesis of an all syn polyketide stereotriad.
| Original language | English |
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| Pages (from-to) | 3501-3504 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 50 |
| Issue number | 26 |
| Early online date | 13 Feb 2013 |
| DOIs | |
| Publication status | Published - 04 Apr 2014 |