Highly diastereoselective hydrosilylations of allylic alcohols

M.G. McLaughlin, M.J. Cook

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The highly syn-selective hydrosilylation of allylic alcohols was developed which, following oxidation, provided 1,3 alcohols containing two contiguous stereocentres. Through judicious choice of silane the complementary anti-selective hydrosilylation was also developed. This protocol was applied to the synthesis of an all syn polyketide stereotriad.
Original languageEnglish
Pages (from-to)3501-3504
Number of pages4
JournalChemical Communications
Volume50
Issue number26
DOIs
Publication statusPublished - 04 Apr 2014

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