Hybrid Organic–Inorganic Polyoxometalates: Functionalization of VIV/ VV Nanosized Clusters to Produce Molecular Capsules

John M. Breen, Wolfgang Schmitt

Research output: Contribution to journalArticlepeer-review

118 Citations (Scopus)

Abstract

Functionalization of polyoxovanadate clusters using phosphonate and arsonate ligands results in molecular capsules (see structure; green V, purple P, red O, black C). Through the use of extended homologous ligands, these hybrid organic-inorganic capsules can be successively elongated into tubular molecules.
Original languageEnglish
Pages (from-to)6904–6908
JournalAngewandte Chemie International Edition
Volume47
Issue number36
DOIs
Publication statusPublished - 2008

Keywords

  • cluster compounds
  • coordination compounds
  • polyoxometalates
  • supramolecular chemistry
  • vanadium

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