Hybrid Organic–Inorganic Polyoxometalates: Functionalization of VIV/ VV Nanosized Clusters to Produce Molecular Capsules

John M. Breen; Wolfgang Schmitt

doi:10.1002/anie.200801770

Hybrid Organic–Inorganic Polyoxometalates: Functionalization of VIV/ VV Nanosized Clusters to Produce Molecular Capsules

John M. Breen, Wolfgang Schmitt

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

118 Citations (Scopus)

Abstract

Functionalization of polyoxovanadate clusters using phosphonate and arsonate ligands results in molecular capsules (see structure; green V, purple P, red O, black C). Through the use of extended homologous ligands, these hybrid organic-inorganic capsules can be successively elongated into tubular molecules.

Original language	English
Pages (from-to)	6904–6908
Journal	Angewandte Chemie International Edition
Volume	47
Issue number	36
DOIs	https://doi.org/10.1002/anie.200801770
Publication status	Published - 2008

Keywords

cluster compounds
coordination compounds
polyoxometalates
supramolecular chemistry
vanadium

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10.1002/anie.200801770

http://onlinelibrary.wiley.com/doi/10.1002/anie.200801770/abstract

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title = "Hybrid Organic–Inorganic Polyoxometalates: Functionalization of VIV/ VV Nanosized Clusters to Produce Molecular Capsules",

abstract = "Functionalization of polyoxovanadate clusters using phosphonate and arsonate ligands results in molecular capsules (see structure; green V, purple P, red O, black C). Through the use of extended homologous ligands, these hybrid organic-inorganic capsules can be successively elongated into tubular molecules.",

keywords = "cluster compounds, coordination compounds, polyoxometalates, supramolecular chemistry, vanadium",

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T1 - Hybrid Organic–Inorganic Polyoxometalates: Functionalization of VIV/ VV Nanosized Clusters to Produce Molecular Capsules

AU - Breen, John M.

AU - Schmitt, Wolfgang

PY - 2008

Y1 - 2008

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AB - Functionalization of polyoxovanadate clusters using phosphonate and arsonate ligands results in molecular capsules (see structure; green V, purple P, red O, black C). Through the use of extended homologous ligands, these hybrid organic-inorganic capsules can be successively elongated into tubular molecules.

KW - cluster compounds

KW - coordination compounds

KW - polyoxometalates

KW - supramolecular chemistry

KW - vanadium

U2 - 10.1002/anie.200801770

DO - 10.1002/anie.200801770

M3 - Article

VL - 47

SP - 6904

EP - 6908

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 36

ER -