Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants

Mark Gilmore; Eadaoin N. McCourt; Francis Connolly; Peter Nockemann; Malgorzata Swadzba-Kwasny; John D. Holbrey

doi:10.1021/acssuschemeng.8b04843

Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants

Mark Gilmore, Eadaoin N. McCourt, Francis Connolly, Peter Nockemann, Malgorzata Swadzba-Kwasny, John D. Holbrey

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

238 Downloads (Pure)

Abstract

A low viscosity, hydrophobic eutectic solvent based on trioctylphosphine oxide (TOPO) has been developed, characterized, and it’s use as an extractant demonstrated for liquid-liquid separation of uranyl nitrate from aqueous acid. This strategy of liquefying the active extracting agent as a eutectic liquid, produced liquids that contain an intrinsically concentration of TOPO (ca. 80 wt%, 1.875 moles L–1 at χTOPO = 0.50) and render the use of an organic (hydrocarbon) diluent redundant.

Original language	English
Pages (from-to)	17323-17332
Number of pages	10
Journal	ACS Sustainable Chemistry & Engineering
Volume	6
Issue number	12
Early online date	26 Oct 2018
DOIs	https://doi.org/10.1021/acssuschemeng.8b04843
Publication status	Published - 26 Oct 2018

ASJC Scopus subject areas

Chemistry (miscellaneous)
Chemistry(all)

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10.1021/acssuschemeng.8b04843

Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants
Copyright 2018, ACS. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 12.4 MBLicence: Unspecified

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John Holbrey
- J.Holbrey@qub.ac.uk
Person: Academic

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title = "Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants",

abstract = "A low viscosity, hydrophobic eutectic solvent based on trioctylphosphine oxide (TOPO) has been developed, characterized, and it{\textquoteright}s use as an extractant demonstrated for liquid-liquid separation of uranyl nitrate from aqueous acid. This strategy of liquefying the active extracting agent as a eutectic liquid, produced liquids that contain an intrinsically concentration of TOPO (ca. 80 wt%, 1.875 moles L–1 at χTOPO = 0.50) and render the use of an organic (hydrocarbon) diluent redundant.",

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doi = "10.1021/acssuschemeng.8b04843",

language = "English",

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Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants. / Gilmore, Mark; McCourt, Eadaoin N.; Connolly, Francis; Nockemann, Peter ; Swadzba-Kwasny, Malgorzata ; Holbrey, John D.

In: ACS Sustainable Chemistry & Engineering, Vol. 6, No. 12, 26.10.2018, p. 17323-17332.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants

AU - Gilmore, Mark

AU - McCourt, Eadaoin N.

AU - Connolly, Francis

AU - Nockemann, Peter

AU - Swadzba-Kwasny, Malgorzata

AU - Holbrey, John D.

PY - 2018/10/26

Y1 - 2018/10/26

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AB - A low viscosity, hydrophobic eutectic solvent based on trioctylphosphine oxide (TOPO) has been developed, characterized, and it’s use as an extractant demonstrated for liquid-liquid separation of uranyl nitrate from aqueous acid. This strategy of liquefying the active extracting agent as a eutectic liquid, produced liquids that contain an intrinsically concentration of TOPO (ca. 80 wt%, 1.875 moles L–1 at χTOPO = 0.50) and render the use of an organic (hydrocarbon) diluent redundant.

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DO - 10.1021/acssuschemeng.8b04843

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JF - ACS Sustainable Chemistry & Engineering

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ER -

Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants

Abstract

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John Holbrey

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