Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants

Mark Gilmore, Eadaoin N. McCourt, Francis Connolly, Peter Nockemann, Malgorzata Swadzba-Kwasny, John D. Holbrey

Research output: Contribution to journalArticle

9 Citations (Scopus)
58 Downloads (Pure)

Abstract

A low viscosity, hydrophobic eutectic solvent based on trioctylphosphine oxide (TOPO) has been developed, characterized, and it’s use as an extractant demonstrated for liquid-liquid separation of uranyl nitrate from aqueous acid. This strategy of liquefying the active extracting agent as a eutectic liquid, produced liquids that contain an intrinsically concentration of TOPO (ca. 80 wt%, 1.875 moles L–1 at χTOPO = 0.50) and render the use of an organic (hydrocarbon) diluent redundant.
Original languageEnglish
Pages (from-to)17323-17332
Number of pages10
JournalACS Sustainable Chemistry & Engineering
Volume6
Issue number12
Early online date26 Oct 2018
DOIs
Publication statusPublished - 26 Oct 2018

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