In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework

Patrick A.  Julien; Krunoslav  Uzarevic ̌; Athanassios D.  Katsenis; Simon A. J.  Kimber; Timothy  Wang; Omar K.  Farha; Yuancheng Zhang; José Casaban; Luzia S.  Germann; Martin  Etter; Robert E.  Dinnebier; Stuart James; Ivan  Halasz; Tomislav  Frisčic

doi:10.1021/jacs.5b13038

In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework

Patrick A. Julien, Krunoslav Uzarevic ̌ , Athanassios D. Katsenis, Simon A. J. Kimber, Timothy Wang, Omar K. Farha, Yuancheng Zhang, José Casaban, Luzia S. Germann, Martin Etter, Robert E. Dinnebier, Stuart James, Ivan Halasz, Tomislav Frisčic

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

121 Citations (Scopus)

Abstract

Mechanochemistry provides a rapid, efficient route to metal organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent. In situ synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.

Original language	English
Pages (from-to)	2929-2932
Journal	Journal of the American Chemical Society (JACS)
Volume	138
Early online date	19 Feb 2016
DOIs	https://doi.org/10.1021/jacs.5b13038
Publication status	Published - 09 Mar 2016

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Julien, P. A., Uzarevic ̌ , K., Katsenis, A. D., Kimber, S. A. J., Wang, T., Farha, O. K., Zhang, Y., Casaban, J., Germann, L. S., Etter, M., Dinnebier, R. E., James, S., Halasz, I., & Frisčic, T. (2016). In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework. Journal of the American Chemical Society (JACS), 138 , 2929-2932. https://doi.org/10.1021/jacs.5b13038

Julien, Patrick A. ; Uzarevic ̌ , Krunoslav ; Katsenis, Athanassios D. ; Kimber, Simon A. J. ; Wang, Timothy ; Farha, Omar K. ; Zhang, Yuancheng ; Casaban, José ; Germann, Luzia S. ; Etter, Martin ; Dinnebier, Robert E. ; James, Stuart ; Halasz, Ivan ; Frisčic, Tomislav . / In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework. In: Journal of the American Chemical Society (JACS). 2016 ; Vol. 138 . pp. 2929-2932.

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title = "In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework",

abstract = "Mechanochemistry provides a rapid, efficient route to metal organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent. In situ synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.",

author = "Julien, {Patrick A.} and {Uzarevic{\v }}, Krunoslav and Katsenis, {Athanassios D.} and Kimber, {Simon A. J.} and Timothy Wang and Farha, {Omar K.} and Yuancheng Zhang and Jos{\'e} Casaban and Germann, {Luzia S.} and Martin Etter and Dinnebier, {Robert E.} and Stuart James and Ivan Halasz and Tomislav Fris{\v c}ic",

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month = mar,

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doi = "10.1021/jacs.5b13038",

language = "English",

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journal = "Journal of the American Chemical Society",

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Julien, PA, Uzarevic ̌ , K, Katsenis, AD, Kimber, SAJ, Wang, T, Farha, OK, Zhang, Y, Casaban, J, Germann, LS, Etter, M, Dinnebier, RE, James, S, Halasz, I & Frisčic, T 2016, 'In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework', Journal of the American Chemical Society (JACS), vol. 138 , pp. 2929-2932. https://doi.org/10.1021/jacs.5b13038

In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework. / Julien, Patrick A.; Uzarevic ̌ , Krunoslav ; Katsenis, Athanassios D. ; Kimber, Simon A. J.; Wang, Timothy ; Farha, Omar K. ; Zhang, Yuancheng; Casaban, José; Germann, Luzia S. ; Etter, Martin ; Dinnebier, Robert E. ; James, Stuart; Halasz, Ivan ; Frisčic, Tomislav .

In: Journal of the American Chemical Society (JACS), Vol. 138 , 09.03.2016, p. 2929-2932.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework

AU - Julien, Patrick A.

AU - Uzarevic ̌ , Krunoslav

AU - Katsenis, Athanassios D.

AU - Kimber, Simon A. J.

AU - Wang, Timothy

AU - Farha, Omar K.

AU - Zhang, Yuancheng

AU - Casaban, José

AU - Germann, Luzia S.

AU - Etter, Martin

AU - Dinnebier, Robert E.

AU - James, Stuart

AU - Halasz, Ivan

AU - Frisčic, Tomislav

PY - 2016/3/9

Y1 - 2016/3/9

N2 - Mechanochemistry provides a rapid, efficient route to metal organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent. In situ synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.

AB - Mechanochemistry provides a rapid, efficient route to metal organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent. In situ synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.

U2 - 10.1021/jacs.5b13038

DO - 10.1021/jacs.5b13038

M3 - Article

VL - 138

SP - 2929

EP - 2932

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

ER -

In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework

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