Inclusions between large flat organic molecules; the induction of columns and mesophases

Klaus Praefcke*, John D. Holbrey

*Corresponding author for this work

Research output: Contribution to journalArticle

69 Citations (Scopus)

Abstract

We describe here an overview on the formation of mesophases by the interaction between large flat aromatic cored molecules and relatively small organic electron acceptors which form stacked, sandwich-like columnar π-π electron donor-acceptor complexes. The inclusion of suitable donor and acceptor components may be used to induce columnar mesophases in mixtures of compounds which can be either mesomorphic or non-mesomorphic in the pure state. With judicious choice of donor and acceptor partners, induced mesophases of remarkable range and thermal stability can be prepared.

Original languageEnglish
Pages (from-to)19-41
Number of pages23
JournalJournal of Inclusion Phenomena and Molecular Recognition in Chemistry
Volume24
Issue number1-2
DOIs
Publication statusPublished - 01 Jan 1996
Externally publishedYes

Keywords

  • Arenes
  • Electron donor-acceptor complexes
  • Heterocycles
  • Induction phenomena
  • Liquid crystals
  • Metallomesogens
  • Radial multiynes

ASJC Scopus subject areas

  • Food Science
  • Chemistry(all)
  • Condensed Matter Physics

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