Investigation of the effect of the preparation method on the activity and stability of Au/CeZrO4 catalysts for the low temperature water gas shift reaction

R. Pilasombat; Helen Daly; Alexandre Goguet; John Breen; Robbie Burch; Christopher Hardacre; D. Thompsett

doi:10.1016/j.cattod.2011.04.053

Investigation of the effect of the preparation method on the activity and stability of Au/CeZrO4 catalysts for the low temperature water gas shift reaction

R. Pilasombat, Helen Daly, Alexandre Goguet, John Breen, Robbie Burch, Christopher Hardacre, D. Thompsett

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The impact of the preparation method on the activity and stability of gold supported on ceria-zirconia low temperature water-gas shift (WGS) catalysts have been investigated. The influence of the gold deposition method, nature of the gold precursor, nature of the washing solution, drying method, Ce: Zr ratio of the support and sulfation of the support have been evaluated. The highest activity catalysts were obtained using a support with a Ce: Zr mole ratio 1: 1, HAuCl4 as the gold precursor deposited via deposition precipitation using sodium carbonate as the precipitation agent and the catalyst washed with water or 0.1 M NH4OH solution. In addition, the drying used was found to be critical with drying under vacuum at room temperature found to be most effective.

Original language	English
Pages (from-to)	131-138
Number of pages	8
Journal	Catalysis Today
Volume	180
Issue number	1
DOIs	https://doi.org/10.1016/j.cattod.2011.04.053
Publication status	Published - 17 Jan 2012

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1016/j.cattod.2011.04.053

Cite this

@article{41adb1e41a474473829f07fabfaf977f,

title = "Investigation of the effect of the preparation method on the activity and stability of Au/CeZrO4 catalysts for the low temperature water gas shift reaction",

abstract = "The impact of the preparation method on the activity and stability of gold supported on ceria-zirconia low temperature water-gas shift (WGS) catalysts have been investigated. The influence of the gold deposition method, nature of the gold precursor, nature of the washing solution, drying method, Ce: Zr ratio of the support and sulfation of the support have been evaluated. The highest activity catalysts were obtained using a support with a Ce: Zr mole ratio 1: 1, HAuCl4 as the gold precursor deposited via deposition precipitation using sodium carbonate as the precipitation agent and the catalyst washed with water or 0.1 M NH4OH solution. In addition, the drying used was found to be critical with drying under vacuum at room temperature found to be most effective.",

author = "R. Pilasombat and Helen Daly and Alexandre Goguet and John Breen and Robbie Burch and Christopher Hardacre and D. Thompsett",

year = "2012",

month = jan,

day = "17",

doi = "10.1016/j.cattod.2011.04.053",

language = "English",

volume = "180",

pages = "131--138",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Investigation of the effect of the preparation method on the activity and stability of Au/CeZrO4 catalysts for the low temperature water gas shift reaction

AU - Pilasombat, R.

AU - Daly, Helen

AU - Goguet, Alexandre

AU - Breen, John

AU - Burch, Robbie

AU - Hardacre, Christopher

AU - Thompsett, D.

PY - 2012/1/17

Y1 - 2012/1/17

N2 - The impact of the preparation method on the activity and stability of gold supported on ceria-zirconia low temperature water-gas shift (WGS) catalysts have been investigated. The influence of the gold deposition method, nature of the gold precursor, nature of the washing solution, drying method, Ce: Zr ratio of the support and sulfation of the support have been evaluated. The highest activity catalysts were obtained using a support with a Ce: Zr mole ratio 1: 1, HAuCl4 as the gold precursor deposited via deposition precipitation using sodium carbonate as the precipitation agent and the catalyst washed with water or 0.1 M NH4OH solution. In addition, the drying used was found to be critical with drying under vacuum at room temperature found to be most effective.

AB - The impact of the preparation method on the activity and stability of gold supported on ceria-zirconia low temperature water-gas shift (WGS) catalysts have been investigated. The influence of the gold deposition method, nature of the gold precursor, nature of the washing solution, drying method, Ce: Zr ratio of the support and sulfation of the support have been evaluated. The highest activity catalysts were obtained using a support with a Ce: Zr mole ratio 1: 1, HAuCl4 as the gold precursor deposited via deposition precipitation using sodium carbonate as the precipitation agent and the catalyst washed with water or 0.1 M NH4OH solution. In addition, the drying used was found to be critical with drying under vacuum at room temperature found to be most effective.

U2 - 10.1016/j.cattod.2011.04.053

DO - 10.1016/j.cattod.2011.04.053

M3 - Article

SN - 0920-5861

VL - 180

SP - 131

EP - 138

JO - Catalysis Today

JF - Catalysis Today

IS - 1

ER -

Investigation of the effect of the preparation method on the activity and stability of Au/CeZrO4 catalysts for the low temperature water gas shift reaction

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this