Ionic liquids as solvents for near-infrared emitting lanthanide complexes

K. Driesen, Peter Nockemann, K. Binnemans

Research output: Contribution to journalArticle

81 Citations (Scopus)

Abstract

It is shown that ionic liquids are promising solvents for near-infrared emitting lanthanide complexes, because ionic liquids are polar non-coordinating solvents that can solubilize lanthanide complexes. Neodymium(III) tosylate, bromide, triflate and sulfonylimide complexes were dissolved in 1-alkyl-3-methylimidazolium ionic liquids that contain the same anion as the neodymium(III) complexes. Near-infrared luminescence spectra of these neodymium(III) salts were measured by direct excitation of the neodymium(III) ion. The absorption spectra show detailed crystal-field fine structure and Judd-Ofelt parameters have been determined. Intense near-infrared luminescence was observed upon ligand excitation for neodymium(III) complexes with 1,10-phenanthroline or beta-diketonate ligands. (C) 2004 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)306-310
Number of pages5
JournalChemical Physics Letters
Volume395
Issue number4-6
DOIs
Publication statusPublished - 11 Sep 2004

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

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