Abstract
tetrabutylphosphonium benzoate, and also exhibits strong complexation with water with both eutectic and peritectic behavior that has not previously been observed in ionic liquid + water systems. The anhydrous and trihydrate salts were isolated and characterized by single crystal X-ray diffraction.
| Original language | English |
|---|---|
| Pages (from-to) | 3384-3389 |
| Number of pages | 6 |
| Journal | ChemPhysChem |
| Volume | 18 |
| Issue number | 23 |
| Early online date | 29 Aug 2017 |
| DOIs | |
| Publication status | Published - 06 Dec 2017 |
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LCST-phase behavior and complexation with water of an ionic liquid incorporating the 5-phenyltetrazolate anion. / Moura, Leila; Brown, Lucy C.; Blesic, Marijana; Holbrey, John D.
In: ChemPhysChem, Vol. 18, No. 23, 06.12.2017, p. 3384-3389.Research output: Contribution to journal › Article
TY - JOUR
T1 - LCST-phase behavior and complexation with water of an ionic liquid incorporating the 5-phenyltetrazolate anion
AU - Moura, Leila
AU - Brown, Lucy C.
AU - Blesic, Marijana
AU - Holbrey, John D.
PY - 2017/12/6
Y1 - 2017/12/6
N2 - The use of 5-phenyltetrazole, a bioisostere of benzoic acid, as an anion source to prepare an ionic liquid is described for the first time. Tetrabutylphosphonium 5-phenyltetrazolate undergoes phase separation from water with lower critical solution temperature phase behavior, in contrast to completely water miscibletetrabutylphosphonium benzoate, and also exhibits strong complexation with water with both eutectic and peritectic behavior that has not previously been observed in ionic liquid + water systems. The anhydrous and trihydrate salts were isolated and characterized by single crystal X-ray diffraction.
AB - The use of 5-phenyltetrazole, a bioisostere of benzoic acid, as an anion source to prepare an ionic liquid is described for the first time. Tetrabutylphosphonium 5-phenyltetrazolate undergoes phase separation from water with lower critical solution temperature phase behavior, in contrast to completely water miscibletetrabutylphosphonium benzoate, and also exhibits strong complexation with water with both eutectic and peritectic behavior that has not previously been observed in ionic liquid + water systems. The anhydrous and trihydrate salts were isolated and characterized by single crystal X-ray diffraction.
U2 - 10.1002/cphc.201700942
DO - 10.1002/cphc.201700942
M3 - Article
VL - 18
SP - 3384
EP - 3389
JO - Chemphyschem : a European journal of chemical physics and physical chemistry
JF - Chemphyschem : a European journal of chemical physics and physical chemistry
SN - 1439-4235
IS - 23
ER -