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Abstract
The use of 5-phenyltetrazole, a bioisostere of benzoic acid, as an anion source to prepare an ionic liquid is described for the first time. Tetrabutylphosphonium 5-phenyltetrazolate undergoes phase separation from water with lower critical solution temperature phase behavior, in contrast to completely water miscible
tetrabutylphosphonium benzoate, and also exhibits strong complexation with water with both eutectic and peritectic behavior that has not previously been observed in ionic liquid + water systems. The anhydrous and trihydrate salts were isolated and characterized by single crystal X-ray diffraction.
tetrabutylphosphonium benzoate, and also exhibits strong complexation with water with both eutectic and peritectic behavior that has not previously been observed in ionic liquid + water systems. The anhydrous and trihydrate salts were isolated and characterized by single crystal X-ray diffraction.
Original language | English |
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Pages (from-to) | 3384-3389 |
Number of pages | 6 |
Journal | ChemPhysChem |
Volume | 18 |
Issue number | 23 |
Early online date | 29 Aug 2017 |
DOIs | |
Publication status | Published - 06 Dec 2017 |
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
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Dive into the research topics of 'LCST-phase behavior and complexation with water of an ionic liquid incorporating the 5-phenyltetrazolate anion'. Together they form a unique fingerprint.Projects
- 1 Finished
Student theses
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Ionic liquids for main group catalysis
Author: Brown, L., Jul 2020Supervisor: Holbrey, J. (Supervisor) & Swadzba-Kwasny, M. (Supervisor)
Student thesis: Doctoral Thesis › Doctor of Philosophy
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Profiles
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Leila Moura
- School of Chemistry and Chemical Engineering - Lecturer and Royal Academy of Engineering Research Fellow
Person: Research
Research output
- 5 Citations
- 3 Article
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Solution structure of propane and propene dissolved in the ionic liquid 1-butyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide from neutron diffraction with H/D substitution and Empirical Potential Structure Refinement modelling
Moura, L., Gilmore, M., Callear, S., Youngs, T. & Holbrey, J., 03 Aug 2019, (Early online date) In: Molecular Physics.Research output: Contribution to journal › Article › peer-review
Open AccessFile104 Downloads (Pure) -
Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants
Gilmore, M., McCourt, E. N., Connolly, F., Nockemann, P., Swadzba-Kwasny, M. & Holbrey, J. D., 26 Oct 2018, In: ACS Sustainable Chemistry & Engineering. 6, 12, p. 17323-17332 10 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile40 Citations (Scopus)818 Downloads (Pure) -
An introduction to zwitterionic salts
Blesic, M., Gilmore, B. F., Holbrey, J. D., Jacquemin, J., Level, G., Nockemann, P. & Stella, L., 07 Sep 2017, In: Green Chemistry. 19, 17, p. 4007-4011 5 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile9 Citations (Scopus)726 Downloads (Pure)