Liquid clathrate formation in ionic liquid-aromatic mixtures

John Holbrey; W.M. Reichert; Mark Nieuwenhuyzen; O. Sheppard; Christopher Hardacre; R.D. Rogers

doi:10.1039/b212726a

Liquid clathrate formation in ionic liquid-aromatic mixtures

John Holbrey
, W.M. Reichert
, Mark Nieuwenhuyzen
, O. Sheppard
, Christopher Hardacre
, R.D. Rogers

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

425 Citations (Scopus)

Abstract

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate-benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2: 1 inclusion compound.

Original language	English
Pages (from-to)	476-477
Number of pages	2
Journal	Chemical Communications
Volume	*
Issue number	4
DOIs	https://doi.org/10.1039/b212726a
Publication status	Published - 21 Feb 2003

ASJC Scopus subject areas

General Chemistry

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10.1039/b212726a

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title = "Liquid clathrate formation in ionic liquid-aromatic mixtures",

abstract = "1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate-benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2: 1 inclusion compound.",

author = "John Holbrey and W.M. Reichert and Mark Nieuwenhuyzen and O. Sheppard and Christopher Hardacre and R.D. Rogers",

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AU - Holbrey, John

AU - Reichert, W.M.

AU - Nieuwenhuyzen, Mark

AU - Sheppard, O.

AU - Hardacre, Christopher

AU - Rogers, R.D.

PY - 2003/2/21

Y1 - 2003/2/21

N2 - 1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate-benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2: 1 inclusion compound.

AB - 1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate-benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2: 1 inclusion compound.

UR - https://www.scopus.com/pages/publications/0037459012

U2 - 10.1039/b212726a

DO - 10.1039/b212726a

M3 - Article

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VL - *

SP - 476

EP - 477

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Liquid clathrate formation in ionic liquid-aromatic mixtures

Abstract

ASJC Scopus subject areas

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