Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry

Samuel Bradberry; Garret Dee; Oxana Kotova; Colin P. McCoy; Thorfinnur Gunnlaugsson

doi:10.1039/c8cc08888h

Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry

Samuel Bradberry, Garret Dee, Oxana Kotova, Colin P. McCoy, Thorfinnur Gunnlaugsson

School of Pharmacy

Research output: Contribution to journal › Article

7 Citations (Scopus)

38 Downloads (Pure)

Abstract

Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.

Original language	English
Pages (from-to)	1754-1757
Journal	Chemical Communications
Volume	55
Issue number	12
DOIs	https://doi.org/10.1039/c8cc08888h
Publication status	Published - 04 Jan 2019

Fingerprint

Keywords

LUMINESCENCE
Lanthanides
HYDROGELS
COPOLYMERS
LIGANDS

Cite this

Bradberry, S., Dee, G., Kotova, O., McCoy, C. P., & Gunnlaugsson, T. (2019). Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry. Chemical Communications, 55(12), 1754-1757. https://doi.org/10.1039/c8cc08888h

@article{8a6f8cab4703490ba29480b234646346,

title = "Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry",

abstract = "Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.",

keywords = "LUMINESCENCE, Lanthanides, HYDROGELS, COPOLYMERS, LIGANDS",

author = "Samuel Bradberry and Garret Dee and Oxana Kotova and McCoy, {Colin P.} and Thorfinnur Gunnlaugsson",

year = "2019",

month = jan,

day = "4",

doi = "10.1039/c8cc08888h",

language = "English",

volume = "55",

pages = "1754--1757",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry

AU - Bradberry, Samuel

AU - Dee, Garret

AU - Kotova, Oxana

AU - McCoy, Colin P.

AU - Gunnlaugsson, Thorfinnur

PY - 2019/1/4

Y1 - 2019/1/4

N2 - Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.

AB - Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.

KW - LUMINESCENCE

KW - Lanthanides

KW - HYDROGELS

KW - COPOLYMERS

KW - LIGANDS

UR - http://www.scopus.com/inward/record.url?scp=85061114368&partnerID=8YFLogxK

U2 - 10.1039/c8cc08888h

DO - 10.1039/c8cc08888h

M3 - Article

C2 - 30664130

AN - SCOPUS:85061114368

VL - 55

SP - 1754

EP - 1757

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 12

ER -

Access to Document

10.1039/c8cc08888hLicence: Unspecified

Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry
Copyright 2019 RSC. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 3.62 MBLicence: Unspecified

Link to publication in Scopus