Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry

Samuel Bradberry; Garret Dee; Oxana Kotova; Colin P. McCoy; Thorfinnur Gunnlaugsson

doi:10.1039/c8cc08888h

Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry

Samuel Bradberry, Garret Dee, Oxana Kotova, Colin P. McCoy, Thorfinnur Gunnlaugsson

School of Pharmacy

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

113 Downloads (Pure)

Abstract

Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.

Original language	English
Pages (from-to)	1754-1757
Journal	Chemical Communications
Volume	55
Issue number	12
DOIs	https://doi.org/10.1039/c8cc08888h
Publication status	Published - 04 Jan 2019

Keywords

LUMINESCENCE
Lanthanides
HYDROGELS
COPOLYMERS
LIGANDS

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c8cc08888hLicence: Unspecified

Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry
Copyright 2019 RSC. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 3.62 MBLicence: Unspecified

Cite this

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abstract = "Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.",

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AU - Bradberry, Samuel

AU - Dee, Garret

AU - Kotova, Oxana

AU - McCoy, Colin P.

AU - Gunnlaugsson, Thorfinnur

PY - 2019/1/4

Y1 - 2019/1/4

N2 - Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.

AB - Two lanthanide luminescent naphthyl-dipicolinic amide (dpa) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu(iii) emission from the hydrogels.

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KW - Lanthanides

KW - HYDROGELS

KW - COPOLYMERS

KW - LIGANDS

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JO - Chemical Communications

JF - Chemical Communications

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Luminescent lanthanide (Eu(iii)) cross-linked supramolecular metallo co-polymeric hydrogels: The effect of ligand symmetry

Abstract

Keywords

ASJC Scopus subject areas

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