Magnetic-field effects on methane-hydrate kinetics and potential geophysical implications: Insights from non-equilibrium molecular dynamics

Niall J English, Christopher C R Allen

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Abstract

We have conducted non-equilibrium molecular-dynamics (NEMD) simulation to show that externally-applied magnetic fields, including their reversals in direction, have important effects on gas-release dynamics from methane hydrates. In particular, we apply fluctuation-dissipation analysis in the guise of Onsager's hypothesis to study hydrate kinetics at lower applied-field intensities, including temporary hydrate destabilisation in the wake of field-polarity switch; we scale down to the lowest practicable field intensities, of the order of 1 T. We conjecture, that these NEMD-based findings, particularly those involving polarity switch, may have ramifications for superchron-related Earth's magnetic-field polarity swaps affecting methane release into the geosphere, although a good deal of further work would be needed to provide a more definitive causal link.

Original languageEnglish
Pages (from-to)664-669
JournalThe Science of the Total Environment
Volume661
Early online date06 Jan 2019
DOIs
Publication statusEarly online date - 06 Jan 2019

Bibliographical note

Copyright © 2019. Published by Elsevier B.V.

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