TY - JOUR
T1 - Magnetic-field effects on methane-hydrate kinetics and potential geophysical implications: Insights from non-equilibrium molecular dynamics
AU - English, Niall J
AU - Allen, Christopher C R
N1 - Copyright © 2019. Published by Elsevier B.V.
PY - 2019/1/6
Y1 - 2019/1/6
N2 - We have conducted non-equilibrium molecular-dynamics (NEMD) simulation to show that externally-applied magnetic fields, including their reversals in direction, have important effects on gas-release dynamics from methane hydrates. In particular, we apply fluctuation-dissipation analysis in the guise of Onsager's hypothesis to study hydrate kinetics at lower applied-field intensities, including temporary hydrate destabilisation in the wake of field-polarity switch; we scale down to the lowest practicable field intensities, of the order of 1 T. We conjecture, that these NEMD-based findings, particularly those involving polarity switch, may have ramifications for superchron-related Earth's magnetic-field polarity swaps affecting methane release into the geosphere, although a good deal of further work would be needed to provide a more definitive causal link.
AB - We have conducted non-equilibrium molecular-dynamics (NEMD) simulation to show that externally-applied magnetic fields, including their reversals in direction, have important effects on gas-release dynamics from methane hydrates. In particular, we apply fluctuation-dissipation analysis in the guise of Onsager's hypothesis to study hydrate kinetics at lower applied-field intensities, including temporary hydrate destabilisation in the wake of field-polarity switch; we scale down to the lowest practicable field intensities, of the order of 1 T. We conjecture, that these NEMD-based findings, particularly those involving polarity switch, may have ramifications for superchron-related Earth's magnetic-field polarity swaps affecting methane release into the geosphere, although a good deal of further work would be needed to provide a more definitive causal link.
U2 - 10.1016/j.scitotenv.2019.01.041
DO - 10.1016/j.scitotenv.2019.01.041
M3 - Article
C2 - 30682616
SN - 0048-9697
VL - 661
SP - 664
EP - 669
JO - The Science of the Total Environment
JF - The Science of the Total Environment
ER -