Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platinum diphosphine complexes

Simon Doherty; Peter Goodrich; Christopher Hardacre; He-Kuan Luo; David Rooney; Kenneth Seddon; P. Styring

doi:10.1039/b312761c

Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platinum diphosphine complexes

Simon Doherty, Peter Goodrich, Christopher Hardacre, He-Kuan Luo, David Rooney, Kenneth Seddon, P. Styring

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

78 Citations (Scopus)

Abstract

Asymmetric Diels-Alder reactions using platinum complexes of BINAP, or of conformationally flexible NUPHOS-type diphosphines, have been compared in dichloromethane and selected ionic liquids. Significant enhancements in the enantioselectivity (Deltaee approximate to 20%), as well as reaction rate, were achieved in ionic liquids compared with the organic media.

Original language	English
Pages (from-to)	63-67
Number of pages	5
Journal	Green Chemistry
Volume	6
Issue number	1
DOIs	https://doi.org/10.1039/b312761c
Publication status	Published - Dec 2004

ASJC Scopus subject areas

General Chemistry

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10.1039/b312761c

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abstract = "Asymmetric Diels-Alder reactions using platinum complexes of BINAP, or of conformationally flexible NUPHOS-type diphosphines, have been compared in dichloromethane and selected ionic liquids. Significant enhancements in the enantioselectivity (Deltaee approximate to 20%), as well as reaction rate, were achieved in ionic liquids compared with the organic media.",

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AU - Luo, He-Kuan

AU - Rooney, David

AU - Seddon, Kenneth

AU - Styring, P.

PY - 2004/12

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AB - Asymmetric Diels-Alder reactions using platinum complexes of BINAP, or of conformationally flexible NUPHOS-type diphosphines, have been compared in dichloromethane and selected ionic liquids. Significant enhancements in the enantioselectivity (Deltaee approximate to 20%), as well as reaction rate, were achieved in ionic liquids compared with the organic media.

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Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platinum diphosphine complexes

Abstract

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