Abstract
Mechanochemistry enabled the selective synthesis of the recherche orange polymorph of Wilkinson's catalyst [RhCl(PPh3)(3)]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H-2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.
Original language | English |
---|---|
Pages (from-to) | 8355-8358 |
Journal | Chemical Communications |
Volume | 54 |
Issue number | 60 |
Early online date | 05 Jul 2018 |
DOIs | |
Publication status | Early online date - 05 Jul 2018 |