Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst

Christian Schumacher; Deborah Crawford; Branimir  Raguž; Robert  Glaum; Stuart James; Carsten Bolm; Jose Hernandez

doi:10.1039/C8CC04487B

Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst

Christian Schumacher, Deborah Crawford, Branimir Raguž, Robert Glaum, Stuart James, Carsten Bolm, Jose Hernandez

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Mechanochemistry enabled the selective synthesis of the recherche orange polymorph of Wilkinson's catalyst [RhCl(PPh3)(3)]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H-2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.

Original language	English
Pages (from-to)	8355-8358
Journal	Chemical Communications
Volume	54
Issue number	60
Early online date	05 Jul 2018
DOIs	https://doi.org/10.1039/C8CC04487B
Publication status	Early online date - 05 Jul 2018

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title = "Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst",

abstract = "Mechanochemistry enabled the selective synthesis of the recherche orange polymorph of Wilkinson's catalyst [RhCl(PPh3)(3)]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H-2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.",

author = "Christian Schumacher and Deborah Crawford and Branimir Ragu{\v z} and Robert Glaum and Stuart James and Carsten Bolm and Jose Hernandez",

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Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst. / Schumacher, Christian; Crawford, Deborah; Raguž, Branimir ; Glaum, Robert ; James, Stuart; Bolm, Carsten; Hernandez, Jose.

In: Chemical Communications, Vol. 54, No. 60, 05.07.2018, p. 8355-8358.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst

AU - Schumacher, Christian

AU - Crawford, Deborah

AU - Raguž, Branimir

AU - Glaum, Robert

AU - James, Stuart

AU - Bolm, Carsten

AU - Hernandez, Jose

PY - 2018/7/5

Y1 - 2018/7/5

N2 - Mechanochemistry enabled the selective synthesis of the recherche orange polymorph of Wilkinson's catalyst [RhCl(PPh3)(3)]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H-2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.

AB - Mechanochemistry enabled the selective synthesis of the recherche orange polymorph of Wilkinson's catalyst [RhCl(PPh3)(3)]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H-2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.

U2 - 10.1039/C8CC04487B

DO - 10.1039/C8CC04487B

M3 - Article

VL - 54

SP - 8355

EP - 8358

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 60

ER -