Abstract
Mechanochemistry enabled the selective synthesis of the recherche orange polymorph of Wilkinson's catalyst [RhCl(PPh3)(3)]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen (H-2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.
| Original language | English |
|---|---|
| Pages (from-to) | 8355-8358 |
| Journal | Chemical Communications |
| Volume | 54 |
| Issue number | 60 |
| Early online date | 05 Jul 2018 |
| DOIs | |
| Publication status | Early online date - 05 Jul 2018 |
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Schumacher, C., Crawford, D., Raguž, B., Glaum, R., James, S., Bolm, C., & Hernandez, J. (2018). Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst. Chemical Communications, 54(60), 8355-8358. https://doi.org/10.1039/C8CC04487B