Mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2)

Peter Nockemann; I. Pantenburg; G. Meyer

doi:10.1002/zaac.200700507

Mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2)

Peter Nockemann, I. Pantenburg, G. Meyer

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Single crystals of mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2), were obtained from aqueous solutions of 1,2,4-triazole and Hg(NO3)(2)center dot 2H(2)O. The crystal structure [monoclinic, P2(1)/c (no. 14), a = 499.6(2), b = 1051.2(4), c = 711.1(3) pm, beta = 117.55(1)degrees, Z = 2, R, for 890 reflections with I-0 > 2 sigma(I-0): 0.0369] contains linear centrosymmetric Hg(Imf)(2) molecules with Hg-N distances of only 203.5(7)pm. Two plus two intra- and intermolecular nitrogen atoms add to an effective coordination number of 6.

Original language	English
Pages (from-to)	613-615
Number of pages	3
Journal	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume	634
Issue number	4
DOIs	https://doi.org/10.1002/zaac.200700507
Publication status	Published - Apr 2008

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/zaac.200700507

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title = "Mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2)",

abstract = "Single crystals of mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2), were obtained from aqueous solutions of 1,2,4-triazole and Hg(NO3)(2)center dot 2H(2)O. The crystal structure [monoclinic, P2(1)/c (no. 14), a = 499.6(2), b = 1051.2(4), c = 711.1(3) pm, beta = 117.55(1)degrees, Z = 2, R, for 890 reflections with I-0 > 2 sigma(I-0): 0.0369] contains linear centrosymmetric Hg(Imf)(2) molecules with Hg-N distances of only 203.5(7)pm. Two plus two intra- and intermolecular nitrogen atoms add to an effective coordination number of 6.",

author = "Peter Nockemann and I. Pantenburg and G. Meyer",

year = "2008",

month = apr,

doi = "10.1002/zaac.200700507",

language = "English",

volume = "634",

pages = "613--615",

journal = "ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE",

issn = "1521-3749",

publisher = "Wiley-VCH Verlag",

number = "4",

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TY - JOUR

T1 - Mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2)

AU - Nockemann, Peter

AU - Pantenburg, I.

AU - Meyer, G.

PY - 2008/4

Y1 - 2008/4

N2 - Single crystals of mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2), were obtained from aqueous solutions of 1,2,4-triazole and Hg(NO3)(2)center dot 2H(2)O. The crystal structure [monoclinic, P2(1)/c (no. 14), a = 499.6(2), b = 1051.2(4), c = 711.1(3) pm, beta = 117.55(1)degrees, Z = 2, R, for 890 reflections with I-0 > 2 sigma(I-0): 0.0369] contains linear centrosymmetric Hg(Imf)(2) molecules with Hg-N distances of only 203.5(7)pm. Two plus two intra- and intermolecular nitrogen atoms add to an effective coordination number of 6.

AB - Single crystals of mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2), were obtained from aqueous solutions of 1,2,4-triazole and Hg(NO3)(2)center dot 2H(2)O. The crystal structure [monoclinic, P2(1)/c (no. 14), a = 499.6(2), b = 1051.2(4), c = 711.1(3) pm, beta = 117.55(1)degrees, Z = 2, R, for 890 reflections with I-0 > 2 sigma(I-0): 0.0369] contains linear centrosymmetric Hg(Imf)(2) molecules with Hg-N distances of only 203.5(7)pm. Two plus two intra- and intermolecular nitrogen atoms add to an effective coordination number of 6.

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U2 - 10.1002/zaac.200700507

DO - 10.1002/zaac.200700507

M3 - Article

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JO - ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

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IS - 4

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Mercuric bis(N-imino-methyl-formamidate), Hg(Imf)(2)

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