Mercurous Azide, Hg2(N3)2

Peter Nockemann, Ulrich Cremer, Uwe Ruschewitz, Gerd Meyer*

*Corresponding author for this work

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

White polycrystalline mercurous azide, Hg2(N3) 2, is obtained by combining aqueous solutions of NaN3 and Hg2(NO3)2·2H2O (made viscuous by addition of tetramethoxysilane and heating at 65°C). The crystal structure was solved and refined from X-ray powder diffraction data (monoclinic, P21/n, a = 596.07(2) pm, b = 1259.07(4) pm, c = 357.95(1) pm, β= 103.253(2)°, Z = 2, RB = 0.0519). Solid Hg2(N3)2 contains, essentially, molecules of that composition with Hg-Hg distances of 254.4(3) pm, Hg-N distances of 218(2) pm and Hg-Hg-N angles of 178.7(6)°. Weak intermolecular interactions with Hg-N distances starting at 280(3) pm lead to a three-dimensional structure.

Original languageEnglish
Pages (from-to)2079-2082
Number of pages4
JournalZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume629
Issue number12-13
Publication statusPublished - 01 Dec 2003
Externally publishedYes

Keywords

  • Azides
  • Crystal structure
  • Mercury

ASJC Scopus subject areas

  • Inorganic Chemistry

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    Nockemann, P., Cremer, U., Ruschewitz, U., & Meyer, G. (2003). Mercurous Azide, Hg2(N3)2. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 629(12-13), 2079-2082.