Microscopic Mechanism and Kinetics of Ice Formation at Complex Interfaces: Zooming in on Kaolinite

Gabriele C. Sosso, Tianshu Li, Davide Donadio, Gareth Tribello, Angelos Michaelides

Research output: Contribution to journalArticle

37 Citations (Scopus)
203 Downloads (Pure)

Abstract

Most ice in nature forms because of impurities which boost the exceedingly low nucleation rate of pure supercooled water. However, the microscopic details of ice nucleation on these substances remain largely unknown. Here, we have unraveled the molecular mechanism and the kinetics of ice formation on kaolinite, a clay mineral playing a key role in climate science. We find that the formation of ice at strong supercooling in the presence of this clay is about 20 orders of magnitude faster than homogeneous freezing. The critical nucleus is substantially smaller than that found for homogeneous nucleation and, in contrast to the predictions of classical nucleation theory (CNT), it has a strong two-dimensional character. Nonetheless, we show that CNT describes correctly the formation of ice at this complex interface. Kaolinite also promotes the exclusive nucleation of hexagonal ice, as opposed to homogeneous freezing where a mixture of cubic and hexagonal polytypes is observed.
Original languageEnglish
Pages (from-to)2350-2355
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume7
Issue number12
Early online date06 Jun 2016
DOIs
Publication statusPublished - 2016

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