Abstract
A rapid and stereodefined synthesis of MIDA−boryl vinylsilanes has been achieved through the hydrosilylation of
an alkynylboronic ester. The E products which contain a silyl and boryl group can be selectively cross-coupled in a two-step
bidirectional sequence to provide a rapid and high-yielding synthesis of complex styrenes.
Original language | English |
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Pages (from-to) | 10-13 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 17 |
Issue number | 1 |
Early online date | 16 Dec 2014 |
DOIs | |
Publication status | Published - 02 Jan 2015 |