Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action

Allen J. M. Huxley; Marc Schroder; H. Q. Nimal Gunaratne; A. Prasanna de Silva

doi:10.1002/anie.201310939

Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action

Allen J. M. Huxley, Marc Schroder, H. Q. Nimal Gunaratne, A. Prasanna de Silva

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

312 Downloads (Pure)

Abstract

The fluorophore-spacer₁-receptor₁-spacer₂-receptor₂ system (where receptor₂ alone is photoredox-inactive) shows ionically tunable proton-induced fluorescence off-on switching, which is reminiscent of thermionic triode behavior. This also represents a new extension to modular switch systems based on photoinduced electron transfer (PET) towards the emulation of analogue electronic devices.

Original language	English
Pages (from-to)	3622-3625
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	53
Issue number	14
Early online date	26 Feb 2014
DOIs	https://doi.org/10.1002/anie.201310939
Publication status	Published - 01 Apr 2014

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10.1002/anie.201310939

Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action
2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Final published version, 469 KB

Cite this

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Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action. / Huxley, Allen J. M.; Schroder, Marc; Gunaratne, H. Q. Nimal; de Silva, A. Prasanna.

In: Angewandte Chemie International Edition, Vol. 53, No. 14, 01.04.2014, p. 3622-3625.

Research output: Contribution to journal › Article › peer-review

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Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action

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Amilra De Silva

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Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action

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Amilra De Silva

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