TY - JOUR
T1 - Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo-Ionic Triode Action
AU - Huxley, Allen J. M.
AU - Schroder, Marc
AU - Gunaratne, H. Q. Nimal
AU - de Silva, A. Prasanna
PY - 2014/4/1
Y1 - 2014/4/1
N2 - The fluorophore-spacer1-receptor1-spacer2-receptor2 system (where receptor2 alone is photoredox-inactive) shows ionically tunable proton-induced fluorescence off-on switching, which is reminiscent of thermionic triode behavior. This also represents a new extension to modular switch systems based on photoinduced electron transfer (PET) towards the emulation of analogue electronic devices.
AB - The fluorophore-spacer1-receptor1-spacer2-receptor2 system (where receptor2 alone is photoredox-inactive) shows ionically tunable proton-induced fluorescence off-on switching, which is reminiscent of thermionic triode behavior. This also represents a new extension to modular switch systems based on photoinduced electron transfer (PET) towards the emulation of analogue electronic devices.
UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-84897426598&partnerID=8YFLogxK
U2 - 10.1002/anie.201310939
DO - 10.1002/anie.201310939
M3 - Article
AN - SCOPUS:84897426598
VL - 53
SP - 3622
EP - 3625
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 14
ER -
