Mutual Solubilities of Ammonium-Based Ionic Liquids with Water and with Water/Methanol Mixture

K. Machanová, J. Jacquemin, Z. Wagner, M. Bendová

Research output: Contribution to journalArticle

13 Citations (Scopus)
224 Downloads (Pure)

Abstract

Over the last two decades, ionic liquids have gained importance as alternative solvents to conventional VOCs in the field of homogeneous catalysis. This success is not only due to their ability to dissolve a large amount of metal catalysts, but it is also due to their potential to enhance yields of enantiopure products. The art of preparation of a specific enantiomer is a highly desired one and searched for in pharmaceutical industry. This work presents a study on solubility in water and in water/methanol mixture of a set of ILs composed of the bis (trifluoromethylsulfonyl) imide anion and of the N-alkyl-triethyl-ammonium cation (abbrev. [NR,222][NTf2]) with the alkyl chain R ranging from 6 to 12 carbons. Mutual solubilities between ILs and water, as well as between ILs and methanol/water mixture were investigated in detail. These solubilities were measured using two well-known and accurate experimental techniques based on a volumetric and a cloud-point methods. Both methods enabled us to measure the Tx diagrams reflecting the mutual solubilities between water (or water/methanol) and selected ILs in the temperature range from 293.15 to 338.15 K. The data were fitted by using the modified Flory-Huggins equation proposed by de Sousa and Rebelo and compared also with the prediction carried out by the Cosmo-RS methodology
Original languageEnglish
Pages (from-to)1229-1241
Number of pages13
JournalProcedia Engineering
Volume42
Early online date25 Aug 2012
DOIs
Publication statusPublished - 2012

ASJC Scopus subject areas

  • Engineering(all)

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