NaH mediated isomerisation-allylation reaction of 1,3-substituted propenols

Adam J S Johnston; Mark G. McLaughlin; Jolene P. Reid; Matthew J. Cook

doi:10.1039/C3OB41857J

NaH mediated isomerisation-allylation reaction of 1,3-substituted propenols

Adam J S Johnston, Mark G. McLaughlin, Jolene P. Reid, Matthew J. Cook^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A base mediated isomerisation-allylation protocol of 1,3- disubstituted propenols has been established. The use of diaryl and aryl-silyl substrates is reported alongside the use of substituted allyl bromides. Mechanistic experiments have also been conducted to elucidate the reaction pathway.

Original language	English
Pages (from-to)	7662-7666
Journal	Organic & biomolecular chemistry
Volume	11
Issue number	44
Early online date	03 Oct 2013
DOIs	https://doi.org/10.1039/C3OB41857J
Publication status	Published - 28 Nov 2013

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title = "NaH mediated isomerisation-allylation reaction of 1,3-substituted propenols",

abstract = "A base mediated isomerisation-allylation protocol of 1,3- disubstituted propenols has been established. The use of diaryl and aryl-silyl substrates is reported alongside the use of substituted allyl bromides. Mechanistic experiments have also been conducted to elucidate the reaction pathway.",

author = "Johnston, {Adam J S} and McLaughlin, {Mark G.} and Reid, {Jolene P.} and Cook, {Matthew J.}",

year = "2013",

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doi = "10.1039/C3OB41857J",

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T1 - NaH mediated isomerisation-allylation reaction of 1,3-substituted propenols

AU - Johnston, Adam J S

AU - McLaughlin, Mark G.

AU - Reid, Jolene P.

AU - Cook, Matthew J.

PY - 2013/11/28

Y1 - 2013/11/28

N2 - A base mediated isomerisation-allylation protocol of 1,3- disubstituted propenols has been established. The use of diaryl and aryl-silyl substrates is reported alongside the use of substituted allyl bromides. Mechanistic experiments have also been conducted to elucidate the reaction pathway.

AB - A base mediated isomerisation-allylation protocol of 1,3- disubstituted propenols has been established. The use of diaryl and aryl-silyl substrates is reported alongside the use of substituted allyl bromides. Mechanistic experiments have also been conducted to elucidate the reaction pathway.

U2 - 10.1039/C3OB41857J

DO - 10.1039/C3OB41857J

M3 - Article

SN - 1477-0520

VL - 11

SP - 7662

EP - 7666

JO - Organic & biomolecular chemistry

JF - Organic & biomolecular chemistry

IS - 44

ER -

NaH mediated isomerisation-allylation reaction of 1,3-substituted propenols

Abstract

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