Nickel hexacyanoferrate nanoparticles as a low cost cathode material for lithium-ion batteries

Marzhana Omarova; Aibolat Koishybay; Nulati Yesibolati; Almagul Mentbayeva; Nurzhan Umirov; Kairat Ismailov; Desmond Adair; Moulay Rachid Babaa; Indira Kurmanbayeva; Zhumabay Bakenov

doi:10.1016/j.electacta.2015.10.031

Nickel hexacyanoferrate nanoparticles as a low cost cathode material for lithium-ion batteries

Marzhana Omarova
, Aibolat Koishybay
, Nulati Yesibolati
, Almagul Mentbayeva
, Nurzhan Umirov
, Kairat Ismailov
, Desmond Adair
, Moulay Rachid Babaa
, Indira Kurmanbayeva
, Zhumabay Bakenov^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Potassium nickel hexacyanoferrate KNi[Fe(CN)6] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li+/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10-9 to 10-8 cm2 s-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.

Original language	English
Pages (from-to)	58-63
Number of pages	6
Journal	Electrochimica Acta
Volume	184
Early online date	24 Oct 2015
DOIs	https://doi.org/10.1016/j.electacta.2015.10.031
Publication status	Published - 01 Dec 2015
Externally published	Yes

Bibliographical note

Funding Information: This research was supported by the Research Grant from Nazarbayev University, by a Subproject 157-2013 funded under the Technology Commercialization Project by the World Bank and the Government of the Republic of Kazakhstan and by a research grant 5097/GF4 from the Ministry of Education and Science of Kazakhstan. The authors acknowledge the PI Nazarbayev Research and Innovation System (Dr. K. Baigarin, Mr. M. Moldabek, Mr. Y. Iskakov) for providing administrative support for this work. Publisher Copyright: ï¿½ 2015 Elsevier Ltd.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Galvanostatic Intermittent Titration Technique
Lithium Diffusion Coefficient
Lithium-ion Battery
Nickel Hexacyanoferrate Cathode

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Cite this

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title = "Nickel hexacyanoferrate nanoparticles as a low cost cathode material for lithium-ion batteries",

abstract = "Potassium nickel hexacyanoferrate KNi[Fe(CN)6] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li+/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10-9 to 10-8 cm2 s-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.",

keywords = "Galvanostatic Intermittent Titration Technique, Lithium Diffusion Coefficient, Lithium-ion Battery, Nickel Hexacyanoferrate Cathode",

author = "Marzhana Omarova and Aibolat Koishybay and Nulati Yesibolati and Almagul Mentbayeva and Nurzhan Umirov and Kairat Ismailov and Desmond Adair and Babaa, \{Moulay Rachid\} and Indira Kurmanbayeva and Zhumabay Bakenov",

note = "Funding Information: This research was supported by the Research Grant from Nazarbayev University, by a Subproject 157-2013 funded under the Technology Commercialization Project by the World Bank and the Government of the Republic of Kazakhstan and by a research grant 5097/GF4 from the Ministry of Education and Science of Kazakhstan. The authors acknowledge the PI Nazarbayev Research and Innovation System (Dr. K. Baigarin, Mr. M. Moldabek, Mr. Y. Iskakov) for providing administrative support for this work. Publisher Copyright: {\"i}¿½ 2015 Elsevier Ltd.",

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doi = "10.1016/j.electacta.2015.10.031",

language = "English",

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journal = "Electrochimica Acta",

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AU - Omarova, Marzhana

AU - Koishybay, Aibolat

AU - Yesibolati, Nulati

AU - Mentbayeva, Almagul

AU - Umirov, Nurzhan

AU - Ismailov, Kairat

AU - Adair, Desmond

AU - Babaa, Moulay Rachid

AU - Kurmanbayeva, Indira

AU - Bakenov, Zhumabay

N1 - Funding Information: This research was supported by the Research Grant from Nazarbayev University, by a Subproject 157-2013 funded under the Technology Commercialization Project by the World Bank and the Government of the Republic of Kazakhstan and by a research grant 5097/GF4 from the Ministry of Education and Science of Kazakhstan. The authors acknowledge the PI Nazarbayev Research and Innovation System (Dr. K. Baigarin, Mr. M. Moldabek, Mr. Y. Iskakov) for providing administrative support for this work. Publisher Copyright: ï¿½ 2015 Elsevier Ltd.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Potassium nickel hexacyanoferrate KNi[Fe(CN)6] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li+/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10-9 to 10-8 cm2 s-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.

AB - Potassium nickel hexacyanoferrate KNi[Fe(CN)6] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li+/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10-9 to 10-8 cm2 s-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.

KW - Galvanostatic Intermittent Titration Technique

KW - Lithium Diffusion Coefficient

KW - Lithium-ion Battery

KW - Nickel Hexacyanoferrate Cathode

U2 - 10.1016/j.electacta.2015.10.031

DO - 10.1016/j.electacta.2015.10.031

M3 - Article

SN - 0013-4686

VL - 184

SP - 58

EP - 63

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Nickel hexacyanoferrate nanoparticles as a low cost cathode material for lithium-ion batteries

Abstract

Bibliographical note

UN SDGs

Keywords

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