Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

C.J. Adams; Stuart James; P.R. Raithby

Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

C.J. Adams, Stuart James, P.R. Raithby

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Reaction of trans-[Pt(NC5H4CHBu2n)(2)Cl-2] 1 with an excess of HC=CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBu2n)(2)(C=CR)(2)] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c;when 1 is treated with 1 equiv, of HC=CC6H2(Me)(2)C=CH the polymer [Pt(NC5H4CHBu2n)(2)C=CC6H2Me2C=C](n) is formed, which is soluble in a range of organic solvents.

Original language	English
Pages (from-to)	2155-2156
Number of pages	2
Journal	Chemical Communications
Volume	1997
Publication status	Published - 1997

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@article{bc1826e0bd37415b8b6cafd99a798dbe,

title = "Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors",

abstract = "Reaction of trans-[Pt(NC5H4CHBu2n)(2)Cl-2] 1 with an excess of HC=CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBu2n)(2)(C=CR)(2)] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c;when 1 is treated with 1 equiv, of HC=CC6H2(Me)(2)C=CH the polymer [Pt(NC5H4CHBu2n)(2)C=CC6H2Me2C=C](n) is formed, which is soluble in a range of organic solvents.",

author = "C.J. Adams and Stuart James and P.R. Raithby",

year = "1997",

language = "English",

volume = "1997",

pages = "2155--2156",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

AU - Adams, C.J.

AU - James, Stuart

AU - Raithby, P.R.

PY - 1997

Y1 - 1997

N2 - Reaction of trans-[Pt(NC5H4CHBu2n)(2)Cl-2] 1 with an excess of HC=CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBu2n)(2)(C=CR)(2)] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c;when 1 is treated with 1 equiv, of HC=CC6H2(Me)(2)C=CH the polymer [Pt(NC5H4CHBu2n)(2)C=CC6H2Me2C=C](n) is formed, which is soluble in a range of organic solvents.

AB - Reaction of trans-[Pt(NC5H4CHBu2n)(2)Cl-2] 1 with an excess of HC=CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBu2n)(2)(C=CR)(2)] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c;when 1 is treated with 1 equiv, of HC=CC6H2(Me)(2)C=CH the polymer [Pt(NC5H4CHBu2n)(2)C=CC6H2Me2C=C](n) is formed, which is soluble in a range of organic solvents.

M3 - Article

SN - 1359-7345

VL - 1997

SP - 2155

EP - 2156

JO - Chemical Communications

JF - Chemical Communications

ER -

Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

Abstract

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