Novel thermoplastic starch-clay nanocomposite foams

Meng Chen, Biqiong Chen, Julian R.G. Evans*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

46 Citations (Scopus)

Abstract

Novel thermoplastic starch (TPS)-clay nanocomposite foams were prepared by melt-processing. The use of urea as plasticizer avoids the cracking of TPS during storage and enhances the dispersion of ammonium-treated clay in TPS. X-ray diffraction shows an increase in the basal plane spacings of both natural and treated clays, suggesting formation of nanocomposites. Scanning electron microscopy shows spontaneously formed regular foam structures with 84% porosity in TPS-ammonium-treated clay. This does not form in TPS or TPS-natural clay nanocomposites. This result implies that the regular foam formation is due to the ammonium surfactant of clay, which produces ammonia gas acting as an internal blowing agent. Thermogravimetric analysis confirms this deduction.

Original languageEnglish
Pages (from-to)2334-2337
Number of pages4
JournalNanotechnology
Volume16
Issue number10
DOIs
Publication statusPublished - 01 Oct 2005
Externally publishedYes

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering
  • Electrical and Electronic Engineering

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