OBSERVATION OF BIPHASIC KINETICS IN LIGHT-INDUCED SPIN-STATE CROSSOVER IN AN IRON(II) COMPLEX IN SOLUTION

A.H.R. Alobaidi, J.J. Mcgarvey, Katie Taylor, Steven Bell, K.B. Jensen, H. Toftlund

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Relaxation of the 1A1 half arrow right over half arrow left 5T2 spin equilibrium in acetonitrile of the complex of Fe(II) with the multidentate pyridyl macrocyclic ligand N,N',N''-tris(2-pyridylmethyl)-1,4,7-triazacyclodecane (tp[10]aneN3) after perturbation by a pulsed laser provides the first example of biphasic kinetics for spin crossover in solution with a fast (tau
Original languageEnglish
Pages (from-to)536-538
Number of pages3
JournalChemical Communications
Volume1
Publication statusPublished - 1993

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    Alobaidi, A. H. R., Mcgarvey, J. J., Taylor, K., Bell, S., Jensen, K. B., & Toftlund, H. (1993). OBSERVATION OF BIPHASIC KINETICS IN LIGHT-INDUCED SPIN-STATE CROSSOVER IN AN IRON(II) COMPLEX IN SOLUTION. Chemical Communications, 1, 536-538.