Oligomerisation of linear 1-olefins using a chlorogallate(III) ionic liquid

Martin Atkins; Kenneth Seddon; Malgorzata Swadzba-Kwasny

doi:10.1351/PAC-CON-10-12-03

Oligomerisation of linear 1-olefins using a chlorogallate(III) ionic liquid

Martin Atkins, Kenneth Seddon, Malgorzata Swadzba-Kwasny

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A Lewis acidic chlorogallate(III) ionic liquid, 1-ethyl-3-methylimidazolium hepta-chlorodigallate(III), [C(2)mim][Ga2Cl7], was successfully used to oligomerise 1-pentene. The influence of temperature, time, catalyst concentration, and stirring rate on conversion and product distribution was modelled using a design of experiment (DoE) approach (chemometrics). The process was optimised for lubricant base oils production; the C20-C50 fraction (where Cn indicates the number of carbons in the oligomer) was maximised, while the heavier oligomer fraction (>C50) was minimised.

Original language	English
Pages (from-to)	1391-1406
Number of pages	16
Journal	Pure and Applied Chemistry
Volume	83
Issue number	7
DOIs	https://doi.org/10.1351/PAC-CON-10-12-03
Publication status	Published - 2011

ASJC Scopus subject areas

General Chemical Engineering
General Chemistry

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10.1351/PAC-CON-10-12-03

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title = "Oligomerisation of linear 1-olefins using a chlorogallate(III) ionic liquid",

abstract = "A Lewis acidic chlorogallate(III) ionic liquid, 1-ethyl-3-methylimidazolium hepta-chlorodigallate(III), [C(2)mim][Ga2Cl7], was successfully used to oligomerise 1-pentene. The influence of temperature, time, catalyst concentration, and stirring rate on conversion and product distribution was modelled using a design of experiment (DoE) approach (chemometrics). The process was optimised for lubricant base oils production; the C20-C50 fraction (where Cn indicates the number of carbons in the oligomer) was maximised, while the heavier oligomer fraction (>C50) was minimised.",

author = "Martin Atkins and Kenneth Seddon and Malgorzata Swadzba-Kwasny",

year = "2011",

doi = "10.1351/PAC-CON-10-12-03",

language = "English",

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journal = "Pure and Applied Chemistry",

issn = "1365-3075",

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TY - JOUR

T1 - Oligomerisation of linear 1-olefins using a chlorogallate(III) ionic liquid

AU - Atkins, Martin

AU - Seddon, Kenneth

AU - Swadzba-Kwasny, Malgorzata

PY - 2011

Y1 - 2011

N2 - A Lewis acidic chlorogallate(III) ionic liquid, 1-ethyl-3-methylimidazolium hepta-chlorodigallate(III), [C(2)mim][Ga2Cl7], was successfully used to oligomerise 1-pentene. The influence of temperature, time, catalyst concentration, and stirring rate on conversion and product distribution was modelled using a design of experiment (DoE) approach (chemometrics). The process was optimised for lubricant base oils production; the C20-C50 fraction (where Cn indicates the number of carbons in the oligomer) was maximised, while the heavier oligomer fraction (>C50) was minimised.

AB - A Lewis acidic chlorogallate(III) ionic liquid, 1-ethyl-3-methylimidazolium hepta-chlorodigallate(III), [C(2)mim][Ga2Cl7], was successfully used to oligomerise 1-pentene. The influence of temperature, time, catalyst concentration, and stirring rate on conversion and product distribution was modelled using a design of experiment (DoE) approach (chemometrics). The process was optimised for lubricant base oils production; the C20-C50 fraction (where Cn indicates the number of carbons in the oligomer) was maximised, while the heavier oligomer fraction (>C50) was minimised.

U2 - 10.1351/PAC-CON-10-12-03

DO - 10.1351/PAC-CON-10-12-03

M3 - Article

SN - 1365-3075

VL - 83

SP - 1391

EP - 1406

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

IS - 7

ER -

Oligomerisation of linear 1-olefins using a chlorogallate(III) ionic liquid

Abstract

ASJC Scopus subject areas

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