On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

Alexandre Goguet; Frederic Meunier; Daniele Tibiletti; John Breen; Robbie Burch

doi:10.1039/b403438d

On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

Alexandre Goguet, Frederic Meunier, Daniele Tibiletti, John Breen, Robbie Burch

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

99 Citations (Scopus)

Abstract

The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusionsregarding the reaction mechanism cannot be inferred using ex operando conditions.

Original language	English
Pages (from-to)	1636-1637
Number of pages	2
Journal	Chemical Communications
Volume	2004
Issue number	14
DOIs	https://doi.org/10.1039/b403438d
Publication status	Published - 21 Jun 2004

ASJC Scopus subject areas

General Chemistry

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title = "On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction",

abstract = "The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusionsregarding the reaction mechanism cannot be inferred using ex operando conditions.",

author = "Alexandre Goguet and Frederic Meunier and Daniele Tibiletti and John Breen and Robbie Burch",

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T1 - On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

AU - Goguet, Alexandre

AU - Meunier, Frederic

AU - Tibiletti, Daniele

AU - Breen, John

AU - Burch, Robbie

PY - 2004/6/21

Y1 - 2004/6/21

N2 - The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusionsregarding the reaction mechanism cannot be inferred using ex operando conditions.

AB - The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusionsregarding the reaction mechanism cannot be inferred using ex operando conditions.

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U2 - 10.1039/b403438d

DO - 10.1039/b403438d

M3 - Article

SN - 1359-7345

VL - 2004

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JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

Abstract

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