Origin of Efficient Catalytic Combustion of Methane over Co3O4(110): Active Low-Coordination Lattice Oxygen and Cooperation of Multiple Active Sites 

Wende Hu, Jinggang Lan, Yun Guo, Xiao Ming Cao*, P. Hu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

73 Citations (Scopus)

Abstract

A complete catalytic cycle for methane combustion on the Co3O4(110) surface was investigated and compared with that on the Co3O4(100) surface on the basis of first-principles calculations. It is found that the 2-fold coordinated lattice oxygen (O2c) would be of vital importance for methane combustion over Co3O4 surfaces, especially for the first two C-H bond activations and the C-O bond coupling. It could explain the reason the Co3O4(110) surface significantly outperforms the Co3O4(100) surface without exposed O2c for methane combustion. More importantly, it is found that the cooperation of homogeneous multiple sites for multiple elementary steps would be indispensable. It not only facilitates the hydrogen transfer between different sites for the swift formation of H2O to effectively avoid the passivation of the active low-coordinated O2c site but also stabilizes surface intermediates during the methane oxidation, optimizing the reaction channel. An understanding of this cooperation of multiple active sites not only might be beneficial in developing improved catalysts for methane combustion but also might shed light on one advantage of heterogeneous catalysts with multiple sites in comparison to single-site catalysts for catalytic activity.

Original languageEnglish
Pages (from-to)5508-5519
JournalACS Catalysis
Volume6
Issue number8
DOIs
Publication statusPublished - 05 Aug 2016

Keywords

  • CH bond activation
  • DFT
  • methane combustion
  • multiple active sites
  • spinel cobalt oxides

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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