Phenol recovery from aromatic-rich oils by formation of eutectic liquids with trialkyl-2,3-dihydroxypropylammonium chloride salts

John Holbrey; Emily Byrne

doi:10.3390/suschem1010004

Phenol recovery from aromatic-rich oils by formation of eutectic liquids with trialkyl-2,3-dihydroxypropylammonium chloride salts

John Holbrey
, Emily Byrne

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

197 Downloads (Pure)

Abstract

Trialkyl-2,3-dihydroxypropylammonium chloride salts have been investigated as liquid eutectic-forming salts for the extraction of phenol from aromatic-rich model oil (toluene) demonstrating how increased partitioning of phenol from oil-phases can be combined with reduced co-miscibility of the salt with aromatic hydrocarbons through the introduction of the dihydroxypropyl-function

Original language	English
Pages (from-to)	49-61
Number of pages	13
Journal	Sustainable Chemistry
Volume	1
Issue number	1
DOIs	https://doi.org/10.3390/suschem1010004
Publication status	Published - 09 Jun 2020

Keywords

Deep Eutectic Solvents
Phenol
Extraction
Green Chemistry
Sustainability

Access to Document

10.3390/suschem1010004Licence: CC BY

Phenol recovery from aromatic-rich oils by formation of eutectic liquids with trialkyl-2,3-dihydroxypropylammonium chloride salts
Copyright 2020 the authors. This is an open access article published under a Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Final published version, 301 KBLicence: CC BY
Phenol Recovery from Aromatic Solvents by Formation of Eutectic Liquids with Trialkyl-2,3-dihydroxypropylammonium Chloride Salts
Copyright 2020 the authors. This is an open access article published under a Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Final published version, 344 KBLicence: CC BY

Designing functional liquids
Byrne, E. (Author), Swadzba-Kwasny, M. (Supervisor) & Holbrey, J. (Supervisor), Dec 2021
Student thesis: Doctoral Thesis › Doctor of Philosophy

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8 Citations
2 Article

Enhanced Extraction of Phenol from Model Oils Using Ionic Liquids Elucidated with Neutron Diffraction
Turner, A. H., Byrne, E. L., Pereira, T. & Holbrey, J. D., 08 Apr 2020, In: Physical Chemistry Chemical Physics (PCCP). 22, 18, p. 10219-20226 8 p.
Research output: Contribution to journal › Article › peer-review

Open Access
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12 Link opens in a new tab Citations (Scopus)

207 Downloads (Pure)
Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants
Gilmore, M., McCourt, E. N., Connolly, F., Nockemann, P., Swadzba-Kwasny, M. & Holbrey, J. D., 26 Oct 2018, In: ACS Sustainable Chemistry & Engineering. 6, 12, p. 17323-17332 10 p.
Research output: Contribution to journal › Article › peer-review

Open Access
File
161 Link opens in a new tab Citations (Scopus)

1725 Downloads (Pure)

Cite this

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title = "Phenol recovery from aromatic-rich oils by formation of eutectic liquids with trialkyl-2,3-dihydroxypropylammonium chloride salts",

abstract = "Trialkyl-2,3-dihydroxypropylammonium chloride salts have been investigated as liquid eutectic-forming salts for the extraction of phenol from aromatic-rich model oil (toluene) demonstrating how increased partitioning of phenol from oil-phases can be combined with reduced co-miscibility of the salt with aromatic hydrocarbons through the introduction of the dihydroxypropyl-function",

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AB - Trialkyl-2,3-dihydroxypropylammonium chloride salts have been investigated as liquid eutectic-forming salts for the extraction of phenol from aromatic-rich model oil (toluene) demonstrating how increased partitioning of phenol from oil-phases can be combined with reduced co-miscibility of the salt with aromatic hydrocarbons through the introduction of the dihydroxypropyl-function

KW - Deep Eutectic Solvents

KW - Phenol

KW - Extraction

KW - Green Chemistry

KW - Sustainability

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Phenol recovery from aromatic-rich oils by formation of eutectic liquids with trialkyl-2,3-dihydroxypropylammonium chloride salts

Abstract

Keywords

Access to Document

Fingerprint

Student theses

Designing functional liquids

Research output

Enhanced Extraction of Phenol from Model Oils Using Ionic Liquids Elucidated with Neutron Diffraction

Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants

Cite this