Preparation and characterisation of palladium, platinum and manganese di(organo)carbene complexes from quinolinone and quinolinium precursors

WH Meyer, M Deetlefs, M Pohlmann, R Scholz, MW Esterhuysen, GR Julius, HG Raubenheimer*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

A series of palladium, platinum and manganese di(organo) carbene complexes have been prepared from 4-chloro-N-methylquinolinone by processes that involve alkylation before or after attachment to the metal unit; the nucleophilic heteroatoms necessary for eventual carbene formation and stabilisation are separated from the C-donor atom by three bonds.

Original languageEnglish
Pages (from-to)413-420
Number of pages8
JournalDalton Transactions
Issue number3
DOIs
Publication statusPublished - 2004

Keywords

  • PROMOTED CYCLIZATION REACTIONS
  • N-HETEROCYCLIC CARBENES
  • X-RAY-STRUCTURE
  • TRANSITION-METAL
  • MOLECULAR-STRUCTURE
  • CRYSTAL
  • LIGANDS
  • DERIVATIVES

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