PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

Mark G. McLaughlin; Matthew J. Cook

doi:10.1039/c1cc14433b

PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

Mark G. McLaughlin, Matthew J. Cook

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

A highly regioselective hydrosilylation of propargylic alcohols has been developed using an in situ prepared PtCl2/XPhos catalyst system. The reaction is tolerant of many functional groups and exhibits excellent regio and geometric selectivity.

Original language	English
Pages (from-to)	11104-11106
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	39
DOIs	https://doi.org/10.1039/c1cc14433b https://doi.org/10.1039/C1CC14433B
Publication status	Published - 21 Oct 2011

ASJC Scopus subject areas

Catalysis
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films

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title = "PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols",

abstract = "A highly regioselective hydrosilylation of propargylic alcohols has been developed using an in situ prepared PtCl2/XPhos catalyst system. The reaction is tolerant of many functional groups and exhibits excellent regio and geometric selectivity.",

author = "McLaughlin, {Mark G.} and Cook, {Matthew J.}",

year = "2011",

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doi = "10.1039/c1cc14433b",

language = "English",

volume = "47",

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journal = "Chemical Communications",

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T1 - PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

AU - McLaughlin, Mark G.

AU - Cook, Matthew J.

PY - 2011/10/21

Y1 - 2011/10/21

N2 - A highly regioselective hydrosilylation of propargylic alcohols has been developed using an in situ prepared PtCl2/XPhos catalyst system. The reaction is tolerant of many functional groups and exhibits excellent regio and geometric selectivity.

AB - A highly regioselective hydrosilylation of propargylic alcohols has been developed using an in situ prepared PtCl2/XPhos catalyst system. The reaction is tolerant of many functional groups and exhibits excellent regio and geometric selectivity.

UR - http://dx.doi.org/10.1039/C1CC14433B

U2 - 10.1039/c1cc14433b

DO - 10.1039/c1cc14433b

M3 - Article

SN - 1359-7345

VL - 47

SP - 11104

EP - 11106

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

Abstract

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