A highly regioselective hydrosilylation of propargylic alcohols has been developed using an in situ prepared PtCl2/XPhos catalyst system. The reaction is tolerant of many functional groups and exhibits excellent regio and geometric selectivity.
ASJC Scopus subject areas
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
- Materials Chemistry
- Metals and Alloys
- Surfaces, Coatings and Films
McLaughlin, M. G., & Cook, M. J. (2011). PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols. Chemical Communications, 47(39), 11104-11106. https://doi.org/10.1039/c1cc14433b