Recent advances in the catalytic generation of N-acyliminium ions and subsequent applications

Ashley J. Basson; Mark G. McLaughlin

doi:10.1016/j.tet.2022.132764

Recent advances in the catalytic generation of N-acyliminium ions and subsequent applications

Ashley J. Basson
, Mark G. McLaughlin

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

155 Downloads (Pure)

Abstract

N-acyliminium ions are highly electrophilic reactive intermediates which allow functionalization α to an amide or carbamate. Traditionally accessed using stoichiometric quantities, catalytic generation continually offers greater control and selectivity. This review provides an overview of the most recent advancements in catalytic access to N-acyliminium ions using Brønsted acid, Lewis acid, photoredox and redox mediated pathways.

Original language	English
Article number	132764
Journal	Tetrahedron
Volume	114
Early online date	06 May 2022
DOIs	https://doi.org/10.1016/j.tet.2022.132764
Publication status	Published - 21 May 2022
Externally published	Yes

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10.1016/j.tet.2022.132764Licence: CC BY

Recent advances in the catalytic generation of N-acyliminium ions and subsequent applications
Copyright 2022 the authors. This is an open access article published under a Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Final published version, 2.76 MBLicence: CC BY

Cite this

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abstract = "N-acyliminium ions are highly electrophilic reactive intermediates which allow functionalization α to an amide or carbamate. Traditionally accessed using stoichiometric quantities, catalytic generation continually offers greater control and selectivity. This review provides an overview of the most recent advancements in catalytic access to N-acyliminium ions using Br{\o}nsted acid, Lewis acid, photoredox and redox mediated pathways.",

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N2 - N-acyliminium ions are highly electrophilic reactive intermediates which allow functionalization α to an amide or carbamate. Traditionally accessed using stoichiometric quantities, catalytic generation continually offers greater control and selectivity. This review provides an overview of the most recent advancements in catalytic access to N-acyliminium ions using Brønsted acid, Lewis acid, photoredox and redox mediated pathways.

AB - N-acyliminium ions are highly electrophilic reactive intermediates which allow functionalization α to an amide or carbamate. Traditionally accessed using stoichiometric quantities, catalytic generation continually offers greater control and selectivity. This review provides an overview of the most recent advancements in catalytic access to N-acyliminium ions using Brønsted acid, Lewis acid, photoredox and redox mediated pathways.

U2 - 10.1016/j.tet.2022.132764

DO - 10.1016/j.tet.2022.132764

M3 - Article

SN - 0040-4020

VL - 114

JO - Tetrahedron

JF - Tetrahedron

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ER -

Recent advances in the catalytic generation of N-acyliminium ions and subsequent applications

Abstract

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