Abstract
Earlier ab initio calculations for electron scattering by HCl are analysed to obtain the behaviour of the S-matrix poles as the internuclear distance is varied. It is shown that the pole which corresponds to a bound state at large internuclear distances does not evolve into a resonance as the distance is decreased but moves on to a lower Riemann sheet where it will have no observable effect on scattering cross sections. The resonance which was observed near 3 eV is shown to correspond to a different, unrelated pole.
Original language | English |
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Article number | 006 |
Journal | Journal of Physics B: Atomic, Molecular and Optical Physics |
Volume | 23 |
Issue number | 15 |
DOIs | |
Publication status | Published - 01 Dec 1990 |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics