Resonance Raman and surface-enhanced resonance Raman studies of polymer-modified electrodes which mimic heme enzymes

Steven Bell, M.D. Devenney, J. Grimshaw, S. Hara, J.H. Rice, J. Trocha-Grimshaw

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Iron-5,10,15,20-tetraphenylporphyrin (FeTPP) has been incorporated into films of a coordinating hydrogel polymer support medium, poly(gamma-ethyl-L-glutamate) (PEG) functionalised with imidazole pendant arms (PEG-Im), and studied in situ on silver electrodes using a combination of both resonance Raman (RR) and surface-enhanced resonance Raman (SERR) spectroscopy. The SERR spectra give information on the portion of the film close to the electrode surface while RR spectra probe the
Original languageEnglish
Pages (from-to)2955-2960
Number of pages6
JournalJournal of the Chemical Society - Faraday Transactions
Volume94
Issue number19
Publication statusPublished - 1998

Fingerprint

Heme
enzymes
Polymers
Electrodes
electrodes
polymers
Enzymes
Polyethylene glycols
Raman scattering
Raman spectra
glutamates
Hydrogel
imidazoles
Silver
Raman spectroscopy
Glutamic Acid
Iron
silver
iron
probes

Cite this

Bell, Steven ; Devenney, M.D. ; Grimshaw, J. ; Hara, S. ; Rice, J.H. ; Trocha-Grimshaw, J. / Resonance Raman and surface-enhanced resonance Raman studies of polymer-modified electrodes which mimic heme enzymes. In: Journal of the Chemical Society - Faraday Transactions. 1998 ; Vol. 94, No. 19. pp. 2955-2960.
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Resonance Raman and surface-enhanced resonance Raman studies of polymer-modified electrodes which mimic heme enzymes. / Bell, Steven; Devenney, M.D.; Grimshaw, J.; Hara, S.; Rice, J.H.; Trocha-Grimshaw, J.

In: Journal of the Chemical Society - Faraday Transactions, Vol. 94, No. 19, 1998, p. 2955-2960.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Resonance Raman and surface-enhanced resonance Raman studies of polymer-modified electrodes which mimic heme enzymes

AU - Bell, Steven

AU - Devenney, M.D.

AU - Grimshaw, J.

AU - Hara, S.

AU - Rice, J.H.

AU - Trocha-Grimshaw, J.

PY - 1998

Y1 - 1998

N2 - Iron-5,10,15,20-tetraphenylporphyrin (FeTPP) has been incorporated into films of a coordinating hydrogel polymer support medium, poly(gamma-ethyl-L-glutamate) (PEG) functionalised with imidazole pendant arms (PEG-Im), and studied in situ on silver electrodes using a combination of both resonance Raman (RR) and surface-enhanced resonance Raman (SERR) spectroscopy. The SERR spectra give information on the portion of the film close to the electrode surface while RR spectra probe the

AB - Iron-5,10,15,20-tetraphenylporphyrin (FeTPP) has been incorporated into films of a coordinating hydrogel polymer support medium, poly(gamma-ethyl-L-glutamate) (PEG) functionalised with imidazole pendant arms (PEG-Im), and studied in situ on silver electrodes using a combination of both resonance Raman (RR) and surface-enhanced resonance Raman (SERR) spectroscopy. The SERR spectra give information on the portion of the film close to the electrode surface while RR spectra probe the

M3 - Article

VL - 94

SP - 2955

EP - 2960

JO - Journal of the Chemical Society - Faraday Transactions

JF - Journal of the Chemical Society - Faraday Transactions

SN - 0956-5000

IS - 19

ER -